The initial discovery by Bednorz and Muller1 of 35-K superconductivity in the La-Ba-Cu-O system has stimulated worldwide activity in searching for higher-temperature superconductors. Elemental substitution has proved to be most effective in raising transition temperature. Substitution of Sr for Ba has produced 40-K superconductivity2–5and substitution of Y for La has produced a new high-temperature superconductor with transition temperature above liquid-nitrogen temperature6. A class of superconducting compounds of the form RBa2Cu307-x has been explored by further substitutions of other rare earths (Y is considered in the rare-earth [RI category here) for Y7-13. To date, a rare earth, an alkaline earth, copper and oxygen have been required for all high-temperature superconductors14,15. (Zhanget al 14reported 90-K superconductivity in the Th-Ba-Pb(Zr)-Cu-O system. Panetal15reported 50-K superconductivity in the Y-Ba-Ag-O system. As Th is a member of the actinide series which belongs to the same Group 3B in the periodic table as the lanthanide series and Ag belongs to the same Group 1B as Cu, high-temperature supercon-ductors are still thought to be closed in the Group 3B—Group 2A-Group 1B—oxygen system. ) Only partial substitutions ha. e led to superconductors, but with no significant rise of transition tem-perature (the only exception is 40-K superconductivity in La2CuO4-x , refs 16, 17). Here we report superconductivity in the rare-earth-free TI-Ba-Cu-O system. We have obsened sharp drops of resistance starting above 90 K with zero resistance at 81 K in this system. Magnetic measurements have confirmed that these sharp drops of resistance in the TI-Ba-Cu-O samples origi-nate from superconductivity. The samples are stable in air for at least two months, and their preparation is easily reproduced.

Superconductivity in the rare-earth-free Tl–Ba–Cu–O system above liquid-nitrogen temperature

An extensive review is given of the results from literature on electron beam induced deposition. Electron beam induced deposition is a complex process, where many and often mutually dependent factors are involved. The process has been studied by many over many years in many different experimental setups, so it is not surprising that there is a great variety of experimental results. To come to a better understanding of the process, it is important to see to which extent the experimental results are consistent with each other and with the existing model. All results from literature were categorized by sorting the data according to the specific parameter that was varied (current density, acceleration voltage, scan patterns, etc.). Each of these parameters can have an effect on the final deposit properties, such as the physical dimensions, the composition, the morphology, or the conductivity. For each parameter-property combination, the available data are discussed and (as far as possible) interpreted. By combining models for electron scattering in a solid, two different growth regimes, and electron beam induced heating, the majority of the experimental results were explained qualitatively. This indicates that the physical processes are well understood, although quantitatively speaking the models can still be improved. The review makes clear that several major issues remain. One issue encountered when interpreting results from literature is the lack of data. Often, important parameters (such as the local precursor pressure) are not reported, which can complicate interpretation of the results. Another issue is the fact that the cross section for electron induced dissociation is unknown. In a number of cases, a correlation between the vertical growth rate and the secondary electron yield was found, which suggests that the secondary electrons dominate the dissociation rather than the primary electrons. Conclusive evidence for this hypothesis has not been found. Finally, there is a limited understanding of the mechanism of electron induced precursor dissociation. In many cases, the deposit composition is not directly dependent on the stoichiometric composition of the precursor and the electron induced decomposition paths can be very different from those expected from calculations or thermal decomposition. The dissociation mechanism is one of the key factors determining the purity of the deposits and a better understanding of this process will help develop electron beam induced deposition into a viable nanofabrication technique.

/pdf/a-critical-literature-review-of-focused-electron-beam-21cjric9ud.pdf

A critical literature review of focused electron beam induced deposition

In order to clarify the effect of metal oxide support on the catalytic activity of gold for CO oxidation, gold has been deposited on SiO2 with high dispersion by chemical vapor deposition (CVD) of an organo-gold complex. Comparison of Au/SiO2 with Au/Al2O3 and Au/TiO2, which were prepared by both CVD and liquid phase methods, showed that there were no appreciable differences in their catalytic activities as far as gold is deposited as nanoparticles with strong interaction. The perimeter interface around gold particles in contact with the metal oxide supports appears to be essential for the genesis of high catalytic activities at low temperatures.

Chemical vapor deposition of gold on Al2O3, SiO2, and TiO2 for the oxidation of CO and of H2

A thorough discussion of the various features of the photoluminescence spectra of undoped, p‐doped and n‐doped AlxGa1−xAs (0≤x≤1) alloys is given. This review covers spectral features in the energy region ranging from the energy band gap down to ≂0.8 eV, doping densities from isolated impurities to strongly interacting impurities (heavy‐doping effects) and lattice temperatures from 2 to 300 K. The relevance of photoluminescence as a simple but very powerful characterization technique is stressed also in comparison with other experimental methods. The most recent determinations of the Al concentration dependence of some physical properties of the alloy (energy gaps, carrier effective masses, dielectric constants, phonon energies, donor and acceptor binding energies, etc.) are given. The main physical mechanisms of the radiative recombination process in semiconductors are summarized with particular emphasis on the experimental data available for AlxGa1−xAs. The effects of the nature of the band gap (direct ...

Photoluminescence of AlxGa1−xAs alloys

The present disclosure relates to a semiconductor light emitting device, comprising: a plurality of semiconductor layers, including a first semiconductor layer having a first conductivity, a second semiconductor layer having a second conductivity different from the first conductivity, and an active layer interposed between the first semiconductor layer and the second semiconductor layer, generating light via electron-hole recombination; a first electrode, supplying either electrons or holes to the plurality of semiconductor layers; a second electrode, supplying, to the plurality of semiconductor layers, electrons if the holes are supplied by the first electrode, or holes if the electrons are supplied by the first electrode; a non-conductive distributed bragg reflector coupled to the plurality of semiconductor layers, reflecting the light from the active layer; and a first light-transmitting film coupled to the distributed bragg reflector from a side opposite to the plurality of semiconductor layers with respect to the non-conductive distributed bragg reflector, with the first light-transmitting film having a refractive index lower than an effective refractive index of the distributed bragg reflector.

Semiconductor Light Emitting Device

InGaP crystals grown on (001)GaAs substrates by metalorganic chemical vapor deposition are structurally evaluated by transmission electron microscopy. High-resolution electron microscopy observation and electron diffraction analysis of both the (110) and the (10) cross-section specimens strongly suggest that ordering of column III atoms on only two sets of the (111) planes with doubling in periodicity of (111) layers, i.e., In/Ga/In/Ga/In/Ga. . ., is occurring in the crystal. The ordering of the crystal is not perfect, and the ordered regions are assumed to be plate-like microdomains.

https://iopscience.iop.org/article/10.1143/JJAP.26.L1824/pdf

Atomic Structure of Ordered InGaP Crystals Grown on (001)GaAs Substrates by Metalorganic Chemical Vapor Deposition

Transmission electron microscopic observation of InGaP crystals grown on (001)GaAs substrates by metalorganic chemical vapor deposition

A film-forming device with a substrate rotating mechanism includes a susceptor 30 in the form of a circular disk; a base plate 6 positioned below the susceptor 30 and rotatably retaining the susceptor 30 ; a revolution generating section 5 rotating the susceptor 30 at the outer periphery of the susceptor 30 ; a plurality of substrate tray retaining sections 23 arranged on the susceptor 30 ; a plurality of annular substrate trays 20 rotatably supported in the corresponding substrate tray retaining sections 23 ; a rotation generating section 4 rotating the substrate trays 20 ; and a plurality of substrates W retained in the substrate trays 20 . The substrates W are revolved by the rotation of the susceptor 30 and rotated by the rotation of the substrate trays 20 to apply a certain film-forming process. The substrates W are rotated and revolved by one or more revolution generating section 5 and the rotation generating section 4.

Film-forming device with a substrate rotating mechanism

Pseudomorphic n-InGaP/InGaAs/GaAs grown by MOVPE for HEMT LSIs

We investigated photoionization of deep traps in AlGaAs/GaAs multiple‐quantum‐well layers and measured the photocurrent (PC) parallel to the layers under a small electric field. There is a small shoulder due to the photoionization of a deep trap on the low‐energy side of the n=1 exciton resonance peak in the PC spectra taken as a function of the excitation energy ℏω. The excitation energy dependence f(ℏω) and amplitude A of the photoionization cross section, σ(ℏω)=Af(ℏω), are determined by the time constants of single‐shot PC transients. The excitation energy dependence increases linearly with excitation energy. The photoionization threshold energy EMQWth and the amplitude A increase as well thickness decreases. These characteristics are explained well by our theoretical study on the photoionization of a deep trap to subbands.

Junji Komeno

Papers

Atomic Structure of Ordered InGaP Crystals Grown on (001)GaAs Substrates by Metalorganic Chemical Vapor Deposition

Transmission electron microscopic observation of InGaP crystals grown on (001)GaAs substrates by metalorganic chemical vapor deposition

Film-forming device with a substrate rotating mechanism

Pseudomorphic n-InGaP/InGaAs/GaAs grown by MOVPE for HEMT LSIs

Photoionization of deep traps in AlGaAs/GaAs quantum wells