K.H. Michaelian

TL;DR: The resonance Raman excitation profiles of a number of charge transfer transitions in electron donor/acceptor complexes with tetracyanoethylene as acceptor in solution at room temperature are reported and compared with absorption and fluorescence spectra of these complexes.

TL;DR: In this article, a valence force field calculation for the out-of-plane modes of tetracyanoethylene is reported, which makes possible a straightforward assignment of the low-frequency vibrations, including several inplane modes which previously could not be assigned with certainty.

TL;DR: The Ramaman spectra of liquid mixtures of TCNE with aromatic electron donors were studied in this article, where the electron transfer of up to 9% in the ground state of these complexes was observed.

TL;DR: In this paper, a resonance-enhanced 155−167 cm−1 Raman band was found in TCNE/EDA complexes in solution and was assigned to the totally symmetric νs vibration of uncomplexed TCNE, necessitating a reinterpretation of previously published data.

TL;DR: In this paper, the preresonance Raman intensity enhancement for the νCC and ν CN vibrations of TCNE complexed with toluene, benzene and fluorobenzene is established.