Showing papers by "Kaley A. Walker published in 1997"
01 Jan 1997
TL;DR: The line positions of all these bands, along with those of a few addi- tional bands available in the literature, were combined in a global least squares ® t. as mentioned in this paper.
Abstract: with v  = 0 and 1 and v  = 6 to 12 in the range 15 945± 30 218 cm - 1 were observed and rotationally analysed. The line positions of all these bands, along with those of a few addi- tional bands available in the literature, were combined in a global least-squares ® t. Many molecular parameters for the various vibrational levels and the equilibrium molecular con- stants for the X and A states were estimated. RKR potential energy curves were constructed and Franck± Condon factors were calculated for the vibrational bands of the second negative (A± X) system. Some additional information obtained from threshold photoelectron spectro- scopy was used to extend the X 2 P g potential curve up to v = 24.