There is, I think, something ethereal about i —the square root of minus one. I remember first hearing about it at school. It seemed an odd beast at that time—an intruder hovering on the edge of reality.

Usually familiarity dulls this sense of the bizarre, but in the case of i it was the reverse: over the years the sense of its surreal nature intensified. It seemed that it was impossible to write mathematics that described the real world in …

I and i

Over the past three decades a new spectroscopic technique with unique possibilities has emerged. Based on coherent and time-resolved detection of the electric field of ultrashort radiation bursts in the far-infrared, this technique has become known as terahertz time-domain spectroscopy (THz-TDS). In this review article the authors describe the technique in its various implementations for static and time-resolved spectroscopy, and illustrate the performance of the technique with recent examples from solid-state physics and physical chemistry as well as aqueous chemistry. Examples from other fields of research, where THz spectroscopic techniques have proven to be useful research tools, and the potential for industrial applications of THz spectroscopic and imaging techniques are discussed.

Terahertz spectroscopy and imaging – Modern techniques and applications

Visible Light Communication (VLC) is an emerging field in Optical Wireless Communication (OWC) which utilizes the superior modulation bandwidth of Light Emitting Diodes (LEDs) to transmit data. In modern day communication systems, the most popular frequency band is Radio Frequency (RF) mainly due to little interference and good coverage. However, the rapidly dwindling RF spectrum along with increasing wireless network traffic has substantiated the need for greater bandwidth and spectral relief. By combining illumination and communication, VLC provides ubiquitous communication while addressing the shortfalls and limitations of RF communication. This paper provides a comprehensive survey on VLC with an emphasis on challenges faced in indoor applications over the period 1979–2014. VLC is compared with infrared (IR) and RF systems and the necessity for using this beneficial technology in communication systems is justified. The advantages of LEDs compared to traditional lighting technologies are discussed and comparison is done between different types of LEDs currently available. Modulation schemes and dimming techniques for indoor VLC are discussed in detail. Methods needed to improve VLC system performance such as filtering, equalization, compensation, and beamforming are also presented. The recent progress made by various research groups in this field is discussed along with the possible applications of this technology. Finally, the limitations of VLC as well as the probable future directions are presented.

LED Based Indoor Visible Light Communications: State of the Art

Terahertz (THz) science and technology have greatly progressed over the past two decades to a point where the THz region of the electromagnetic spectrum is now a mature research area with many fundamental and practical applications. Furthermore, THz imaging is positioned to play a key role in many industrial applications, as THz technology is steadily shifting from university-grade instrumentation to commercial systems. In this context, the objective of this review is to discuss recent advances in THz imaging with an emphasis on the modalities that could enable real-time high-resolution imaging. To this end, we first discuss several key imaging modalities developed over the years: THz transmission, reflection, and conductivity imaging; THz pulsed imaging; THz computed tomography; and THz near-field imaging. Then, we discuss several enabling technologies for real-time THz imaging within the time-domain spectroscopy paradigm: fast optical delay lines, photoconductive antenna arrays, and electro-optic sampling with cameras. Next, we discuss the advances in THz cameras, particularly THz thermal cameras and THz field-effect transistor cameras. Finally, we overview the most recent techniques that enable fast THz imaging with single-pixel detectors: mechanical beam-steering, compressive sensing, spectral encoding, and fast Fourier optics. We believe that this critical and comprehensive review of enabling hardware, instrumentation, algorithms, and potential applications in real-time high-resolution THz imaging can serve a diverse community of fundamental and applied scientists.

Toward real-time terahertz imaging

Vibrational spectroscopy has continued use as a powerful tool to characterize ionic liquids since the literature on room temperature molten salts experienced the rapid increase in number of publications in the 1990’s. In the past years, infrared (IR) and Raman spectroscopies have provided insights on ionic interactions and the resulting liquid structure in ionic liquids. A large body of information is now available concerning vibrational spectra of ionic liquids made of many different combinations of anions and cations, but reviews on this literature are scarce. This review is an attempt at filling this gap. Some basic care needed while recording IR or Raman spectra of ionic liquids is explained. We have reviewed the conceptual basis of theoretical frameworks which have been used to interpret vibrational spectra of ionic liquids, helping the reader to distinguish the scope of application of different methods of calculation. Vibrational frequencies observed in IR and Raman spectra of ionic liquids based on...

Vibrational Spectroscopy of Ionic Liquids

The National Institute of Information and Communications Technology (NICT, Japan) started the Terahertz Project in April 2006. Its fundamental purpose in the next five years is to enable a nationwide technical infrastructure to be created for diverse applications of terahertz technology. The technical infrastructure includes the development of semiconductor devices such as terahertz quantum cascade lasers, terahertz-range quantum well photodetectors, and high-precision tunable continuous wave sources. It also includes pulsed terahertz measurement systems, modeling and measurement of atmospheric propagation, and the establishment of a framework to construct a materials database in the terahertz range including standardization of the measurement protocol. These are common technical infrastructure even in any terahertz systems. In this article, we report the current status of developments in these fields such as terahertz quantum cascade lasers (THz-QCLs) (with peak power of 30 mW, 3.1 THz), terahertz-range quantum well photodetectors (THz-QWPs) (tuned at 3 THz) an ultrawideband terahertz time domain spectroscopy (THz-TDS) system (with measurement range of from 0.1 to 15 THz), an example of a database for materials of fine art, and results obtained from measuring atmospheric propagation.

At the Dawn of a New Era in Terahertz Technology

The authors present a review of the advances that have been made to establish terahertz applications in the cultural heritage conservation sector over the last several years. This includes material spectroscopy, 2D and 3D imaging and tomographic studies, using a broad range of terahertz sources demonstrating the breadth and application of this burgeoning community.

A Survey of Terahertz Applications in Cultural Heritage Conservation Science

Terahertz spectroscopy has rapidly progressed, and is being applied to various research fields as a new non-invasive examination method. Scientific analysis is important for the conservation of art, as it can help to reveal the history of a work and to determine the proper materials for its restoration. Mid-infrared spectroscopy and X-ray analysis are currently used to identify organic and inorganic materials, respectively. Terahertz spectroscopy is expected to identify composites themselves, and to give clear and direct information for art conservation. We have collected terahertz spectra of various historical and modern materials, and found that terahertz spectroscopy can distinguish the pigments, binders and their mixtures. The experimental results prove that terahertz spectroscopy as a new non-invasive examination method can contribute to art history and to restorations. The material database can also contribute to other fields such as earth science, the printing industry, and the food and pharmaceutical research fields.

https://www.jstage.jst.go.jp/article/elex/4/8/4_8_258/_pdf

Terahertz spectroscopy for art conservation

Terahertz (THz) spectroscopy and imaging have been actively studied in these decades. THz waves (0.1–10 THz) are non-invasive, can penetrate opaque materials, and can be used to obtain fingerprint spectra whose characteristics depend upon molecular and intermolecular behavior. Unlike the mid-infrared region, no commercial spectral library is available for the THz region. Consequently, a spectral database of artists’ materials was developed in order to include THz spectroscopy among conservation science techniques. Most pigments and some synthetic polymers have characteristic fingerprint spectra in the THz region. With this technique most of these materials used in paintings can be identified alone or as paint, a combination of pigments and binders. Although the meaning of the spectral features has so far not been fully explained, previous studies on optical materials suggest that phonon absorption and the behavior of hydrogen bonds contribute to their spectral features. Examples of THz spectra of various art materials are discussed on the basis of measurements obtained using a conventional Fourier transform system.

Kaori Fukunaga

Papers

At the Dawn of a New Era in Terahertz Technology

A Survey of Terahertz Applications in Cultural Heritage Conservation Science

Terahertz spectroscopy for art conservation

Terahertz spectroscopy applied to the analysis of artists’ materials

Innovative non-invasive analysis techniques for cultural heritage using terahertz technology