K
Karin Denk
Researcher at Ludwig Maximilian University of Munich
Publications - 3
Citations - 319
Karin Denk is an academic researcher from Ludwig Maximilian University of Munich. The author has contributed to research in topics: Carbene & Ruthenium. The author has an hindex of 3, co-authored 3 publications receiving 304 citations.
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The first metal complexes of bis(diisopropylamino)carbene: synthesis, structure and ligand properties
TL;DR: In this article, the synthesis of rhodium(I) and iridium (I) complexes of bis(diisopropylamino) carbene was described for the first time.
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N‐Heterocyclic Carbenes, Part 33.[1] Combining Stable NHC and Chelating Pyridinyl‐Alcoholato Ligands: A Ruthenium Catalyst for Applications at Elevated Temperatures
TL;DR: In this paper, two synthetic approaches are presented: reacting the NHC phosphine complex 5 with the chelating ligand or reacting the pyridinyl-alcoholatophosphine complex 3 with a free NHC ligand.
Journal ArticleDOI
Ruthenium alkylidenes: modulation of a new class of catalysts for controlled radical polymerization of vinyl monomers.
François Simal,Sébastien Delfosse,Albert Demonceau,Alfred F. Noels,Karin Denk,Florian J. Kohl,Thomas Weskamp,Wolfgang A. Herrmann +7 more
TL;DR: The results indicate that the catalysts decompose quickly under ATRP conditions, and polymerizations are mediated by both [RuCl2(=CHPh)(L)(L')] complexes and ruthenium species bereft of the benzylidene moiety, through a pathway in which both tricyclohexylphosphane and/or N-heterocyclic carbene ligands remain bound to the metal center.