K
Klemenz Kromm
Researcher at University of Erlangen-Nuremberg
Publications - 11
Citations - 194
Klemenz Kromm is an academic researcher from University of Erlangen-Nuremberg. The author has contributed to research in topics: Diphosphines & Rhenium. The author has an hindex of 8, co-authored 10 publications receiving 184 citations.
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Journal ArticleDOI
Chelating diphosphines that contain a rhenium stereocenter in the backbone: Applications in rhodium-catalyzed enantioselective ketone hydrosilylations and alkene hydrogenations
TL;DR: In this paper, the same authors showed that (S)-6 (63/62/60/92%) and (SReRC)-7 (41/46/58/58%) are higher than those of the diastereomer (S-ReSC)-7, with S enantiomers dominant in all cases.
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Rhenium-Containing Phosphorus Donor Ligands for Palladium-Catalyzed Suzuki Cross-Coupling Reactions: A New Strategy for High-Activity Systems
TL;DR: In this paper, the chiral racemic methyl complex (η5-C5H5)Re(NO)(PPh3)(CH3) is converted to the rhenium-containing phosphorus donor ligands.
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Synthesis, Structure, and Reactivity of Palladacycles That Contain a Chiral Rhenium Fragment in the Backbone: New Cyclometalation and Catalyst Design Strategies
TL;DR: The bromocyclopentadienyl complex [(eta5-C5H4Br)Re(CO)3] is converted to racemic similarly to a published sequence for cyclopentADienyl analogues.
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A New Family of Chelating Diphosphines with a Transition Metal Stereocenter in the Backbone: Novel Applications of “Chiral-at-Rhenium” Complexes in Rhodium-Catalyzed Enantioselective Alkene Hydrogenations
TL;DR: The crystal structures of 6+ PF6- and 12+PF6- are compared to those of 3 and 9, and other rhodium complexes of chelating bis(diphenylphosphines).
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A New Family of Chelating Diphosphines with Transition-Metal and Carbon Stereocenters in the Backbone: A Second-Generation Rhenium-Containing System
TL;DR: The less stable ReC isomer of the enantiomerically pure benzylidene complex (S)-[(η5-C5H5)Re(NO)(PPh3)(CHPh)]+BF4- ((S)-(sc)-6) and PPh2H react to give the phosphonium salt (SReSC)-[ (η 5-C 5H5 )Re( NO)