Iron Catalysis in Organic Synthesis

Recent Advances in the Friedländer Reaction

This review article summarizes the applications of bismuth(III) compounds in organic synthesis since 2002. Although there are an increasing number of reports on applications of bismuth(III) salts in polymerization reactions, and their importance is acknowledged, they are not included in this review. This review is largely organized by the reaction type although some reactions can clearly be placed in multiple sections. While every effort has been made to include all relevant reports in this field, any omission is inadvertent and we apologize in advance for the same (358 references).

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Applications of bismuth(III) compounds in organic synthesis

Benign and highly efficient synthesis of quinolines from 2-aminoarylketone or 2-aminoarylaldehyde and carbonyl compounds mediated by hydrochloric acid in water

In water, Friedlander annulation using Lewis acid-surfactant-combined catalyst provides a mild and efficient route for the synthesis of quinolines. Employing a catalytic amount of scandium tris(dodecyl sulfate) [Sc(O3SOC12H25)3], various polysubstituted and polycyclic quinolines were obtained in exellent yields.

Friedländer Synthesis of Quinolines Using a Lewis Acid‐Surfactant‐Combined Catalyst in Water

The preparation of substituted quinoline derivatives through a Friedlander condensation reaction utilizing the ionic liquid [bmim][BF4] as the reaction medium and iron chloride hexahydrate (FeCl3·6...

Lijun Han

Papers

Green preparation of quinoline derivatives through FeCl3.6H2O catalyzed friedlander reaction in ionic liquids

Green Preparation of Quinoline Derivatives Through FeCl3×6H2O Catalyzed Friedlander Reaction in Ionic Liquids.