Metal complexes of saccharin

Bis(saccharinato)palladium(II) and platinum(II) complexes with 2,2′-bipyridine: Syntheses, structures, spectroscopic, fluorescent and thermal properties

Structural studies of Ni(II), Zn(II) and Cd(II) complexes with saccharinate and 2,2′-bipyridine ligands

X-ray crystal structure and electronic spectrum of the complex [Co(C3H4N2)4(H2O)2](C6H4COSO2N)2

The title compound has been synthesized and its crystal structure determined at room temperature. Cd 2 (Sacch) 4 (Im) 4 , F.W. = 1225.83, monoclinic. Space group: C2/c, Z=4, a=20.065(3)1, A, b = 11.164(4) A, c = 20.697(6) A, β = 94.69(5)°, The coordination polyhedron of Cd(II) correspond to a five-coordinate trigonal-bipyramid. In the title complex, two of the saccharin groups act as monodentate ligands. The other two act as bidentate ligands. The two Cd(II) ions are bridged by the two bidentate saccharin groups and the distance is 4.75 A.

Lin Wenbin

Papers

X-ray crystal structure and spectral study of [Cu(C10H8N2)2(C6H4COSO2N)]· (C6H4COSO2N)·3H2O