The chemistry of gold

Application of 2,6-diphenylpyridine as a tridentate [C∧N∧C] dianionic ligand in organogold(III) chemistry. structural and spectroscopic properties of mono- and binuclear transmetalated gold(III) complexes

A series of novel luminescent cyclometalated Au(III) neutral complexes of the type cis-[(N∧C)AuL] [N∧C = 2-phenylpyridine (ppy), L = 1,1′-biphenyl (1)] and cis-[(N∧C)AuL2] [N∧C = 2-phenylpyridine (...

Stable and tunable phosphorescent neutral cyclometalated Au(III) diaryl complexes.

Based on the well-defined five-membered aryl gold(III) complexes, [Au(tpy)X2] (3a and 3b) and [AuBr(Ph)(tpy)] (7), as well as the aryl gold(III) complex [AuCl2(Ph)(tpy)] (8) (tpy = 2-(o-tolyl)pyridine) as reliable models, we present a detailed study of the mechanism for gold(III)-catalyzed oxidative cross-coupling reactions between cycloaurable arenes and arylboronic acids. Here we report the direct evidence for a mechanistic proposal including arene C–H activation, transmetallation and biaryl reductive elimination. The chelation-assisted C–H activation strategy has been used for the development of the gold(III)-catalyzed C–H bond arylation of arenes with aryl reagents to forge extended π-conjugated systems.

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Stoichiometric to catalytic reactivity of the aryl cycloaurated species with arylboronic acids: insight into the mechanism of gold-catalyzed oxidative C(sp2)–H arylation

Silver and Gold

https://digitum.um.es/digitum/bitstream/10201/76902/1/A%20NEW%20WAY%20OF%20SYNTHESISING%20DIARYLGOLD.pdf

A new way of Synthesising diarylgold(III) Complexes using organomercury compounds

https://digitum.um.es/digitum/bitstream/10201/76904/1/Complexes%20of%20Gold.pdf

Ortho-nitrophenyl complexes of gold(III)

O-nitrophenyl complexes of gold(iii)

o-Nitrophenylpalladium(II) Complexes. Crystal and Molecular Structures of cis-Cyclic (Pd(o-C6H4N(O)O)2) and cis-Cyclic (Pd(o-C6H4N(O)O)(o-C6H4NO2)(py))

M. Artigao

Papers

A new way of Synthesising diarylgold(III) Complexes using organomercury compounds

Ortho-nitrophenyl complexes of gold(III)

O-nitrophenyl complexes of gold(iii)

o-Nitrophenylpalladium(II) Complexes. Crystal and Molecular Structures of cis-Cyclic (Pd(o-C6H4N(O)O)2) and cis-Cyclic (Pd(o-C6H4N(O)O)(o-C6H4NO2)(py))