Steel slag is a byproduct of the steelmaking and steel refining processes. This paper provides an overview of the different types of steel slag that are generated from basic-oxygen-furnace (BOF) steelmaking, electric-arc-furnace (EAF) steelmaking, and ladlefurnace steel refining processes. The mineralogical and morphological properties of BOF and electric-arc-furnace-ladle [EAF(L)] slag samples generated from two steel plants in Indiana were determined through X-Ray Diffraction (XRD) analyses and Scanning Electron Microscopy (SEM) studies. The XRD patterns of both BOF and EAF(L) slag samples were very complex, with several overlapping peaks resulting from the many minerals present in these samples. The XRD analyses indicated the presence of free MgO and CaO in both the BOF and EAF(L) slag samples. SEM micrographs showed that the majority of the sand-size steel slag particles had subangular to angular shapes. Very rough surface textures with distinct crystal structures were observed on the sandsize particles of BOF and EAF(L) slag samples under SEM. The characteristics of the steel slag samples considered in this study are discussed in the context of a detailed review of steel slag properties.

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Chemical, mineralogical, and morphological properties of steel slag

This report presents information on the characterization of cementitiously stabilized layers and the properties that influence pavement performance. It also contains recommended performance-related procedures for characterizing these layers and performance-prediction models for incorporation into the mechanistic–empirical pavement analysis methods. Individual chapters highlight pavement distresses of hot-mix asphalt pavements and concrete pavements, laboratory tests and model development, and model calibration. The material contained in the report will be of immediate interest to state materials, pavement, and construction engineers and others involved in the different aspects of pavement design and construction.

Characterization of Cementitiously Stabilized Layers for Use in Pavement Design and Analysis

Steel slag is a by-product of steelmaking and refining processes. In 2006, 10-15 million metric ton of steel slag was generated in the U.S. Out of the total steel slag produced in the U.S. every year, about 50-70% is used as aggregate for road and pavement construction and approximately 15-40% is stockpiled in steel plants and eventually landfilled at slag disposal sites. Since current levels of steel slag stockpiling and landfilling are not sustainable, alternative geotechnical engineering applications for steel slag are being explored to alleviate the slag disposal problem and to help save dwindling natural resources. The main objectives of this research were to determine the geotechnical engineering properties of two types of steel slag generated from different steelmaking operations and to assess their potential use in subgrade stabilization and embankment construction. Samples of fresh and aged basic-oxygen-furnace (BOF) slag and of fresh electric-arc-furnace-ladle (EAF(L)) slag were characterized through a series of laboratory tests (specific gravity, grain-size analysis, X-ray diffraction, compaction, maximum and minimum density, large-scale direct shear, consolidated drained triaxial and swelling tests). The effects of gradation on the engineering properties of both fresh and aged steel slag samples were also investigated. Various mixtures of steel slag [BOF and EAF(L)] and Class-C fly ash were also investigated. The mixtures were prepared by adding 5 and 10% Class-C fly ash (by weight) to aged BOF slag and 5, 10 and 20% Class-C fly ash (by weight) to fresh EAF(L) slag. Unconfined compression tests were performed after various curing times to evaluate the strength gain characteristics of the mixtures. Long-term swelling tests were performed for compacted mixtures of both fresh and aged BOF slag and 10% Class-C fly ash (by weight) and for compacted mixtures of fresh EAF(L) slag and 5, 10 and 20% Class-C fly ash (by weight). The effect of adding 10% ground rubber (by weight) to fresh and aged BOF slag on the long-term swelling behavior of the mixtures was also investigated. The optimum moisture content and maximum dry unit weight of BOF slag were in the ranges of 4-8% and 19.5-21.8 kN/m3, respectively. The critical-state friction angle of fresh and aged BOF slags was in the 45.3°- 48.1° range according to large-scale direct shear test results. Based on isotropically consolidated drained triaxial test (CIDTX) results, the peak friction angles of aged BOF slag (with minus 9.5 mm gradation) samples prepared at 90% relative compaction were equal to 47.3°, 45.2° and 43.5° at effective confining stresses of 50, 110 and 200 kPa, respectively. The optimum moisture content and maximum dry unit weight of EAF(L) slag were in the ranges of 10-13% and 16.8-20.0 kN/m3, respectively. The critical-state friction angle of fresh EAF(L) slag was equal to approximately 40.6° according to large-scale direct shear tests results. Compacted mixtures of both Class-C fly ash and BOF slag and of Class-C fly ash and EAF(L) slag showed excellent strength gain properties with time. Results of the long-term swelling tests on steel slag and Class-C fly ash mixtures showed that the addition of 10% Class-C fly ash suppresses the swelling of both BOF and EAF(L) slag samples to negligible levels.

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Use of Steel Slag in Subgrade Applications

The type of steel furnace slag (SFS), including electric arc furnace (EAF) slag, basic oxygen furnace (BOF) slag, ladle metallurgy furnace (LMF) slag, and argon oxygen decarburization (AOD) slag, can significantly affect the composite properties when used as an aggregate or as a supplementary cementitious material in bound applications, such as concretes, mortars, alkali-activated materials, and stabilized soils. This review seeks to collate the findings from the literature to express the variability in material properties and to attempt to explain the source(s) of the variability. It was found that SFS composition and properties can be highly variable, including different compositions on the exterior and interior of a given SFS particle, which can affect bonding conditions and be one source of variability on composite properties. A suite of tests is proposed to better assess a given SFS stock for potential use in bound applications; at a minimum, the SFS should be evaluated for free CaO content, expansion potential, mineralogical composition, cementitious composite mechanical properties, and chemical composition with secondary tests, including cementitious composite durability properties, microstructural characterization, and free MgO content.

A Review of the Influence of Steel Furnace Slag Type on the Properties of Cementitious Composites

Experimental evaluation of EAF ladle steel slag as a geo-fill material: Mineralogical, physical & mechanical properties

The goal of this study was to increase the bearing capacity of cement stabilized soil system by addition of furnace steel slag, which will also result in a consumption of waste produced in large quantities. The results demonstrated the following: The electric arc furnace steel slag with MgO content under 5% can be added in different proportions to a soil-cement system improving strength and conserving cement; the electric arc furnace slag reacts with water and shows a bonding effect that can produce an increase in strength of the soil-cement system at medium and long term; the long term durability of the system is guaranteed because the voids of the soil-cement system are enough to absorb the MgO expansion.

M Barra

Papers

Stabilization of soils with steel slag and cement for application in rural and low traffic roads