M
M. Carmen Blanco
Researcher at University of Zaragoza
Publications - 22
Citations - 1168
M. Carmen Blanco is an academic researcher from University of Zaragoza. The author has contributed to research in topics: Catalysis & Alkyne. The author has an hindex of 13, co-authored 21 publications receiving 1108 citations. Previous affiliations of M. Carmen Blanco include Spanish National Research Council & University of Stuttgart.
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Gold Catalysis: Evidence for the In‐situ Reduction of Gold(III) During the Cyclization of Allenyl Carbinols
TL;DR: In this article, products of an oxidative coupling were obtained in the gold(III)-catalyzed cycloisomerization of tertiary allenyl carbinols, and the absence of reduced organic products and an increase of these coupling products with the amount of gold (III) catalyst suggests that gold( III) is reduced in situ, possibly to gold(I) catalysts which were also shown to be active for these transformations.
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Heterogeneous Gold‐Catalysed Synthesis of Phenols
TL;DR: In this article, the first time that a heterogeneous gold catalyst showed activity in the gold-catalysed phenol synthesis was reported, and the surface bound, cationic gold species is still active and can reach turnover numbers of up to 391.
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Gold Catalysis: First Applications of Cationic Binuclear Gold(I) Complexes and the First Intermolecular Reaction of an Alkyne with a Furan
TL;DR: The reaction of the binuclear gold(I) complex with ω-alkynylfurans furnished phenols as the major product and anellated furans as the side-products as mentioned in this paper.
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Gold-catalyzed benzylic C-H activation at room temperature.
A. Stephen K. Hashmi,Sascha Schäfer,Michael Wölfle,Cesar Diez Gil,Peter Fischer,Antonio Laguna,M. Carmen Blanco,M. Concepción Gimeno +7 more
TL;DR: 4 pages, 7 schemes, 1 figure, 2 tables.-- Supporting information for this article is available: http://www.angewandte.org or from the author.
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The Condensation of Carbonyl Compounds with Electron-Rich Arenes: Mercury, Thallium, Gold or a Proton?
TL;DR: Gold(III) chloride, mercury(II) perchlorate, thallium-III perchlorates and p-toluenesulfonic acid were found to efficiently catalyze the condensation of two furans with aldehydes or acetone as mentioned in this paper.