A single configuration model containing nonorthogonal magnetic orbitals is developed to represent the important features of the antiferromagnetic state of a transition metal dimer. A state of mixed spin symmetry and lowered space symmetry is constructed which has both conceptual and practical computational value. Either unrestricted Hartree–Fock theory or spin polarized density functional theory, e.g., Xα theory, can be used to generate the mixed spin state wave function. The most important consequence of the theory is that the Heisenberg exchange coupling constant J can be calculated simply from the energies of the mixed spin state and the highest pure spin multiplet.

Valence bond description of antiferromagnetic coupling in transition metal dimers

Even the uninitiated will know that Quantum Field Theory cannot be introduced systematically in just four lectures. I try to give a reasonably connected outline of part of it, from second quantization to the path-integral technique in Euclidean space, where there is an immediate connection with the rules for Feynman diagrams and the partition function of Statistical Mechanics.

Introduction to quantum field theory

On the general theory of collisions for particles with spin

We define chiral vertex operators and duality matrices and review the fundamental identities they satisfy. In order to understand the meaning of these equations, and therefore of conformal field theory, we define the classical limit of a conformal field theory as a limit in which the conformal weights of all primary fields vanish. The classical limit of the equations for the duality matrices in rational field theory together with some results of category theory, suggest that (quantum) conformal field theory should be regarded as a generalization of group theory.

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Classical and Quantum Conformal Field Theory

The proton relaxation time in solutions of paramagnetic ions depends, among other factors, on the relaxation time of the electron spins, τs. It is shown that the latter, for ions of the iron group, is determined mostly by the distortion of the hydrated complex by collisions with other water molecules. The theory provides a quantitative explanation for the decrease in T2 in Mn++ (and other) solutions in very high magnetic fields. The experimentally observed field and temperature dependence of the proton relaxation times, T1 and T2, for ions of the iron group is compared with theory and the features which depend on τs are stressed.

M. E. Rose

Papers

Elementary Theory of Angular Momentum