Discreteness-of-charge effects in electrode kinetics

V. SUMMARY To the reader who is only casually familiar with electrochemical measurements based on periodic perturbations, perhaps one of the most surprising aspects of this review is its illustration of the level and scope of influence of the methodology considered. Hopefully, it has been made evident that the literature gives witness to notable growth in the three areas of importance to any experimental method:theory, instrumentation, and application. One finds successful application to chemical systems whose types encompass the entire range of solution chemistry, from the molecule of life (DNA) to the simplest elemental ions. Having never bothered to actually keep a quantitative record of the output, even this writer was rather surprised upon first realizing that a yield in the neighborhood of 100 publications per year has characterized this field in the last 3½ years. Even in the present era of the "information explosion" this must be considered a nontrivial level of activity. Because many scientists, ...

Recent Developments in Alternating Current Polarography

Electrostatic effect of specifically adsorbed electroinactive ions upon electrode processes

Double-layer effects on simple electrode reactions I. The reduction of Eu3+ and Cr3+ in the absence of specific adsorption of the supporting electrolyte☆

M. Sluyters-Rehbach

Papers

Electrode kinetics and double-layer structure: III. The Eu(II)/Eu(III) electrode reaction at the DME in 1 M KCl and 1 M KI base electrolyte solutions

Electrode kinetics and double layer structure: IV. The Eu(II)/Eu(III) electrode reaction at the DME in 1 M KSCN; Influence of complex formation

The interference of shielding and capillary response in the determination of rate parameters of electrode reactions and the double layer capacitance