Showing papers by "M. Sluyters-Rehbach published in 1980"

TL;DR: In this paper, a faradaic impedance study has been made of the reduction of Cd(II) ions from a 1 M KF base electrolyte at the DME.

TL;DR: A largely automatic instrument for the measurement of the admittance of a galvanic cell is described in this article, where the frequency of the alternating voltage and the dc voltage are scanned stepwise in a programmed sequence.

TL;DR: In this article, it was shown that in the whole range of the composition of this base electrolyte the Cd(II) reduction can be explained on the assumption of a reaction mechanism that consists of a chemical step followed by two one-electron transfers, the transfer coefficients appearing to be 0.5.

TL;DR: In this paper, the reduction of oxygen to hydrogen peroxide at a dropping mercury electrode in an aqueous solution of 1 M KNO3+0.04 M KOH (pH=12.35) has been studied by means of impedance measurements as a function of frequency and d.c. potential.

TL;DR: The enhancement of the dc polarographic reduction current of oxygen by adsorbed Pb(II) species first observed by Strnad in 1939 and later studied qualitatively by a number of other authors was reconsidered both experimentally and theoretically as discussed by the authors.