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Showing papers by "M. Sluyters-Rehbach published in 1996"

Journal Article•DOI•
Electrode kinetics and the nature of the metal electrode. Part 1. Zn2+ reduction from aqueous 1 M NaClO4 solution at indium and thallium amalgams of varied composition

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L. Koene1, M. Sluyters-Rehbach1, J.H. Sluyters1•
Utrecht University1
07 Feb 1996-Journal of Electroanalytical Chemistry
TL;DR: In this paper, the kinetic parameters of electron transfer steps in Zn 2+ reduction at dropping indium and thallium amalgam electrodes are obtained as a function of electrode composition and the best correlation found was with the electrical field strength in the inner layer in the amalgam concentration range where the metal phase behaves according to the Sommerfeld free-electron model.

29 citations

Journal Article•DOI•
Electrode kinetics and the nature of the metal electrode. Part 2. The Zn(II)/Zn electrode reaction studied at dropping gallium and mercury ( micro) electrodes

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T.G.J. van Venrooij1, M. Sluyters-Rehbach1, J.H. Sluyters1•
Utrecht University1
05 Dec 1996-Journal of Electroanalytical Chemistry
TL;DR: In this paper, the reduction of Zn(II) from aqueous l M NaClO 4 solution in the presence of 1 mM HClO4 was studied at dropping gallium and mercury electrodes.

18 citations

Journal Article•DOI•
The theory of impedance and demodulation voltammetry for electrode reactions complicated by both activation polarization and reactant adsorption, and their combined application to Tl+ reduction at the DME Part 2

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S.G.J. Blankenborg1, M. Sluyters-Rehbach1, J.H. Sluyters1•
Utrecht University1
24 Jan 1996-Journal of Electroanalytical Chemistry
TL;DR: In this article, a full mathematical description of impedance voltammetry and demodulation voltameters is given for the case where the electrode reaction is activation controlled and is also complicated by reactant adsorption.

10 citations

Journal Article•DOI•
Impedance voltammetric analysis of a consecutive E-C-E mechanism with two diffusing intermediates with application to the reduction of nitromethane

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Francisco Javier García Prieto1, Manuela Rueda1, I. Navarro1, M. Sluyters-Rehbach, J.H. Sluyters •
University of Seville1
12 Apr 1996-Journal of Electroanalytical Chemistry
TL;DR: In this article, the authors derived the faradaic admittance for a consecutive E-C-E mechanism with two stable intermediates with the assumption that the chemical reaction is unidirectional.

9 citations

Journal Article•DOI•
On the potential dependence of the preceding chemical step in the Cd(II) reduction from aqueous KF solutions: a DMμE study

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A. Baars, F.J.C. Bijl, M. Sluyters-Rehbach, J.H. Sluyters
07 Mar 1996-Journal of Electroanalytical Chemistry
TL;DR: In this paper, the reduction of Cd(II) can be studied using dropping mercury microelectrode (DMμE) so that the preceding chemical step is kinetically fully rate-determining.

7 citations