M. Sluyters-Rehbach

TL;DR: In this article, it was shown that the electrical double-layer at a solid electrode does not in general behave as a pure capacitance but rather as an impedance displaying a frequency-independent phase angle different from 90°.

TL;DR: In this paper, a critical study is made of the mathematics needed to describe the current response towards a potential step perturbation of an electrode at which phase formation takes place by the process of nucleation and diffusion-controlled hemispherical growth.

TL;DR: In this article, a critical discussion is presented of some important theories for the electrode impedance in the case that the electroactive species are specifically adsorbed at the electrode-solution interface.

TL;DR: In this paper, the reduction of Zn(II) has been studied by means of the faradaic impedance method in wide potential and frequency ranges and at varied water activity, and the results obtained could be quantitatively explained on the assumption of a mechanism including at least the following consecutive steps: 1 (1) fast partial dehydration of the electroactive species; 2 (2) fast transport from the solution into the double layer; 3 (3) slow transfer of the first electron; 4 (4) a fast second partial dehydration step; 5 (5) slow transferred of the second

TL;DR: In this paper, the reduction of H+ from 1 M FICiO, and 1 IV NaCIO, solurions at polycrystalline and single crystal faces of very pure gold electrode, was studied by determining the forward rate constant kr as a funcrion of porential and of H' concentration.