Through radio frequency glow discharge the molecular structure of a fluoropolymer is permanently modified by the substitution of hydrogen and oxygen or oxygen-containing radicals for fluorine to a depth of up to 100 Å. The surface morphological properties on a molecular level (e.g., pore structure) of the modified fluoropolymer remain substantially uncharged from those of the starting polymer as well as the bulk structure below the modified surface region while wettability with respect to low surface tension liquids and surface free energy as determined through critical surface tension are increased and new chemically reactive sites are created for further wet chemical modification or attachment of various functionality for development of a bioprobe device.

Oxyfluoropolymers having chemically reactive surface functionality and increased surface energies

Pinhole-free thin films deposited by glow discharge or plasma polymerization of organosilanes, organosilazones and organosiloxanes for use as reactive ion etch oxygen barriers in multilayer resist structures, of lift-off masks, for fabrication of semiconductor devices, such as integrated circuits. The process includes deposition of thin plasma polymerized organosilicon barrier film over a radiation insensitive polymeric base layer previously coated on a substrate, followed by thermal annealing of the plasma polymerized barrier layer, over which is then coated a radiation sensitive resist layer. After definition of the desired resist pattern by imagewise exposure and development, the image is etch transferred into the barrier layer by reactive sputter etching in a fluorine containing ambient, and subsequently transferred into the base layer, down to the substrate, in an oxygen plasma, during which time the plasma deposited film functions as an oxygen barrier. Final metal patterns are formed by metallization and lift-off steps.

Use of plasma polymerized organosilicon films in fabrication of lift-off masks

The present invention provides a polymerizable liquid crystal composition containing polymerizable liquid crystal compounds and a photoinitiator, wherein the photoinitiator has a light absorption band in a wavelength range of 280 to 400 nm; and at least one of the polymerizable liquid crystal compounds has a light absorption band in a wavelength range of 320 to 400 nm or a light-absorbing agent having a light absorption band in a wavelength range of 280 to 400 nm is contained. Thus, there is provided a material that can be cured in the air without replacing the atmosphere with an inert gas during irradiation with ultraviolet rays and that can achieve the characteristics required for a biaxial film, such as a sufficiently large front phase difference.

Polymerizable liquid-crystal composition

Non-uniform water-insoluble interpenetrating polymer blend compositions comprising a first permeable water swellable polymer substrate interpenetrated in a gradient substantially normal to the substrate surface by a second less permeable condensation polymer to form a diffusion rate controlling membrane therein. Such compositions are useful as polymers with reduced permeabilities for water and organic solvents and therefore for the controlled delivery of active ingredients such as fragrances and bio-affecting agents into air or aqueous environments, or in membrane separation processes.

Membrane modified hydrogels

The present invention relates to a ultra high molecular weight polyethylene molded article for artificial joints having molecular orientation of crystal orientation and to a method for preparing the same, wherein the polyethylene molded article having a low friction and excellent abrasion resistance is obtained by irradiating a low dose of a radioactive ray to the ultra high molecular weight polyethylene to introduce a small amount of crosslinking points within molecular chains, giving compression-deformation after melting at a high temperature around the melting point thereof, and cooling and solidifying.

Ultra high molecular weight polyethylene molded article for artificial joints and method of preparing the same

A process for producing a semipermeable membrane having a high flux, excellent in solute rejection and useful for reverse osmosis, ultrafiltration and the like which comprises dipping a semipermeable membrane of acrylonitrile polymer containing 40-100% by mole of acrylonitrile in a solution of an amine and/or an alkali, or casting a solution of said polymer containing an amine and/or an alkali to prepare a semipermeable membrane, and optionally, treating the semipermeable membrane thus obtained with plasma.

Process for producing semipermeable membranes

The invention relates to an aromatic liquid-crystalline polyester solution composition comprising 100 parts by weight of a solvent (A) and 0.01 to 100 parts by weight of an aromatic liquid-crystalline polyester (B), wherein the solvent (A) is a solvent containing 30% by weight or more of a chlorine-substituted phenol compound represented by the following general formula (I):

Aromatic liquid-crystalline polyester solution composition

A method for producing a liquid crystalline polyester comprising the steps of acylating phenolic hydroxyl groups of an aromatic diol, an aromatic hydroxycarboxylic acid, or an aromatic diol and aromatichydroxycarboxylic acid with a fatty anhydride to obtain an acylated substance, and trans-esterifying said acylated substance with an aromatic dicarboxylic acid, an aromatic hydroxycarboxylic acid, or an aromatic dicarboxylic acid and aromatic hydroxycarboxylic acid, wherein the acylation, the trans-esterification, or the acylation and trans-esterification is conducted in the presence of a heterocyclic organic base compound containing two or more nitrogen atoms.

Liquid crystalline polyester and method for producing the same

A liquid crystal polyester resin mixture having a stabilized plastication time and accordingly possible to be molded in constant cycles and giving a molded article excellent in mechanical properties and thermal stability is provided. The liquid crystal polyester resin mixture comprises 100 parts by weight of a liquid crystal polyester resin composition which comprises 100 parts by weight of a liquid crystal polyester and from 0 to 150 parts by weight of a filler, and either from 0.001 to 5 parts by weight of a fatty acid amide having a formula; R1—CO—NH2 (wherein R1 denotes a saturated or unsaturated hydrocarbon of 10 to 30 carbons) or from 0.001 to 2 parts by weight of a high molecular weight polyethylene with a molecular weight of 10,000 or higher.

Liquid crystal polyester resin mixture

The object of the present invention is to provide an aromatic polyester amide which has improved mechanical strength and high elastic modulus after being molded into a thin wall article as well as exhibits excellent heat stability and moldability. The present invention provides an aromatic polyester amide comprising the following repeating units (a)-(d): [wherein n in (c) represents 0 or 1] wherein (a) is from 2 to 20 mole %, (b) is from 30 to 65 mole %, (c) is from 15 to 35 mole % and (d) is from 15 to 30 mole % provided that the sum of (a) to (d) is 100 mole %.

Manabu Hirakawa

Papers

Process for producing semipermeable membranes

Aromatic liquid-crystalline polyester solution composition

Liquid crystalline polyester and method for producing the same

Liquid crystal polyester resin mixture

Aromatic polyester amide