High‐Performance [001]c‐Textured PNN‐PZT Relaxor Ferroelectric Ceramics for Electromechanical Coupling Devices

Highly sensitive magnetic field sensor based on a metglas/bidomain lithium niobate composite shaped in form of a tuning fork

Analysis of indentation size effect (ISE) in nanoindentation hardness in polycrystalline PMN-PT piezoceramics with different domain configurations

Lead-free piezoelectric ceramics, (Bi0.70Ba0.35)(Fe0.65Ti0.35)O3 (BBFT), were fabricated via a solid-state reaction method and then treated using different heat-treatment processes (furnace cooling, air quenching (AQ), and water quenching). In all these ceramics, the X-ray diffraction analysis revealed morphotropic phase boundaries between the rhombohedral and tetragonal phases. Changes in the average grain size, relative density, and electrical properties in the BBFT–AQ composition were observed. For the optimum BBFT–AQ ceramic, significantly enhanced dynamic (d33* ~ 340 pm/V) and static (d33 ~ 165 pC/N) piezoelectric coefficients were obtained. Moreover, the d33* increased to 40% (d33* ~ 475 pm/V) with increasing temperature from 25 °C to 75 °C upon the application of a 4.0 kV/mm electric field. The related defect states were established by the variation in the transition of Fe3+ to Fe2+ and OV or $$V_{O}^{ \bullet \bullet }$$
 concentration observed using X-ray photoelectron spectroscopy analysis. These factors are directly related to the electromechanical response enhancement in the BBFT piezoceramics. This study provides a paradigm for a deeper analysis of particular scientific heat-treatment mechanisms and the enhancement of functional properties in BBFT ceramics.

Effect of heat-treatment mechanism on structural and electromechanical properties of eco-friendly (Bi, Ba)(Fe, Ti)O3 piezoceramics

Transparent nano-ceramics have an important high-transmittance, material-integrating structure and function and a variety of potential applications, such as use in infrared windows, optical isolators, composite armors, intelligent terminal screens, and key materials of solid-state lasers. Transparent ceramics were originally developed to replace single crystals because of their low fabricating cost, controllable shape, and variable composition. Therefore, this study reviews and summarizes the development trends in transparent nano-ceramics and their potential applications. First, we review the research progress and application of laser nano-ceramic materials, focusing on the influence of controllable doping of rare earth ions on thermal conductivity and the realization of large-scale fabrication technology. Second, the latest research progress on magneto-optical transparent nano-ceramics, mainly including terbium gallium garnet (Tb3Ga5O12, TGG) ceramics and terbium aluminum garnet (Tb3Al5O12, TAG) ceramics, are summarized, and their performance is compared. Third, the research progress of transparent armor nano-ceramic materials, represented by MgAl2O3 and Aluminum oxynitride (AlON), are reviewed. Lastly, the progress in electro-optical transparent nano-ceramics and scintillation transparent nano-ceramics is reported, and the influence of the material-fabrication process on electro-optic effect or luminous intensity is compared. Moreover, the effect of particle diameter on fabrication, the relationship between nano powder and performance, and different sintering methods are discussed. In summary, this study provides a meaningful reference for low-cost and sustainable production in the future.

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Manoj Kumar Sahukar

Papers

Effect of grain size on piezoelectric, ferroelectric and dielectric properties of PMN-PT ceramics