Showing papers by "Mario Hentschel published in 2023"

Evaporated Self‐Assembled Monolayer Hole Transport Layers: Lossless Interfaces in p‐i‐n Perovskite Solar Cells

Abstract: Engineering of the interface between perovskite absorber thin films and charge transport layers has fueled the development of perovskite solar cells (PSCs) over the past decade. For p‐i‐n PSCs, the development and adoption of hole transport layers utilizing self‐assembled monolayers (SAM‐HTLs) based on carbazole functional groups with phosphonic acid anchoring groups has enabled almost lossless contacts, minimizing interfacial recombination to advance power conversion efficiency in single‐junction and tandem solar cells. However, so far these materials have been deposited exclusively via solution‐based methods. Here, for the first time, vacuum‐based evaporation of the most common carbazole‐based SAM‐HTLs (2PACz, MeO‐2PACz, and Me‐4PACz) is reported. X‐ray photoelectron spectroscopy and infrared spectroscopy demonstrate no observable chemical differences in the evaporated SAMs compared to solution‐processed counterparts. Consequently, the near lossless interfacial properties are either preserved or even slightly improved as demonstrated via photoluminescence measurements and an enhancement in open‐circuit voltage. Strikingly, applying evaporated SAM‐HTLs to complete PSCs demonstrates comparable performance to their solution‐processed counterparts. Furthermore, vacuum deposition is found to improve perovskite wetting and fabrication yield on previously non‐ideal materials (namely Me‐4PACz) and to display conformal and high‐quality coating of micrometer‐sized textured surfaces, improving the versatility of these materials without sacrificing their beneficial properties.

Electrically switchable metallic polymer metasurface device with gel polymer electrolyte

Abstract: Abstract We present an electrically switchable, compact metasurface device based on the metallic polymer PEDOT:PSS in combination with a gel polymer electrolyte. Applying square-wave voltages, we can reversibly switch the PEDOT:PSS from dielectric to metallic. Using this concept, we demonstrate a compact, standalone, and CMOS compatible metadevice. It allows for electrically controlled ON and OFF switching of plasmonic resonances in the 2–3 µm wavelength range, as well as electrically controlled beam switching at angles up to 10°. Furthermore, switching frequencies of up to 10 Hz, with oxidation times as fast as 42 ms and reduction times of 57 ms, are demonstrated. Our work provides the basis towards solid state switchable metasurfaces, ultimately leading to submicrometer-pixel spatial light modulators and hence switchable holographic devices.

Optical reflective metasurfaces based on mirror-coupled slot antennas

Abstract: Abstract. Electrically connected optical metasurfaces with high efficiencies are crucial for developing spatiotemporal metadevices with ultrahigh spatial and ultrafast temporal resolutions. While efficient metal–insulator–metal (MIM) metasurfaces containing discretized meta-atoms require additional electrodes, Babinet-inspired slot-antenna-based plasmonic metasurfaces suffer from low efficiencies and limited phase coverage for copolarized optical fields. Capitalizing on the concepts of conventional MIM and slot-antenna metasurfaces, we design and experimentally demonstrate a new type of optical reflective metasurfaces consisting of mirror-coupled slot antennas (MCSAs). By tuning the dimensions of rectangular-shaped nanoapertures atop a dielectric-coated gold mirror, we achieve efficient phase modulation within a sufficiently large range of 320 deg and realize functional phase-gradient metadevices for beam steering and beam splitting in the near-infrared range. The fabricated samples show (22 % ± 2 % ) diffraction efficiency for beam steering and (17 % ± 1 % ) for beam splitting at the wavelength of 790 nm. The considered MCSA configuration, dispensing with auxiliary electrodes, offers an alternative and promising platform for electrically controlled reflective spatiotemporal metasurfaces.

Dynamic beam control based on electrically switchable nanogratings from conducting polymers

Abstract: Abstract Surging interests in point-of-device miniaturization have led to the development of metasurface-based optical components. Here, we demonstrate an electrically-driven ultracompact beam controller in the infrared spectral range. The effect benefits from diffraction gratings consisting of the commercially available conductive polymer PEDOT:PSS, which exhibits metal-to-insulator transition characteristics upon electrical biasing. By combining several metagratings with different superlattice periods in electrically isolated areas, our device enables diffraction beams at 16 and 33.5° when applying voltages of only ±1 V. Furthermore, no diffraction is realized by switching off the plasmonic property of the gratings. Dynamic control of electromagnetic wave via the presented platforms could be transformative for sensing, imaging, and communication applications.

Electrically switchable metallic polymer metasurfaces for beam switching and multi-focal metaobjectives

Abstract: We demonstrate electrically switchable nanoantennas and metasurfaces from metallic polymers. Such nanoantennas show well-pronounced plasmonic resonances and can be electrically switched fully off and back on by applying CMOS compatible voltages of ±1V. Operation speed is as fast as 30 Hz. Utilizing this concept, we realize, on the one hand, an electrically switchable metallic polymer metasurface for ultra-high-contrast active beam switching. On the other hand, we show an electro-active metaobjective comprising two metalenses-on-demand. By using gel electrolytes, our metadevices can be integrated into state-of-the-art on-chip electro-optic components.

Spatially Resolved Nonlinear Plasmonics.

Abstract: Nonlinear optical plasmonics investigates the emission of plasmonic nanoantennas with the aid of nonlinear spectroscopy. Here we introduce nonlinear spatially resolved spectroscopy (NSRS) which is capable of imaging the k-space as well as spatially resolving the THG signal of gold nanoantennas and investigating the emission of individual antennas by wide-field illumination of entire arrays. Hand in hand with theoretical simulations, we demonstrate our ability of imaging various oscillation modes inside the nanostructures and therefore spatial emission hotspots. Upon increasing intensity of the femtosecond excitation, an individual destruction threshold can be observed. We find certain antennas becoming exceptionally bright. By investigating those samples taking structural SEM images of the nanoantenna arrays afterward, our spatially resolved nonlinear image can be correlated with this data proving that antennas had deformed into a peanut-like shape. Thus, our NSRS setup enables the investigation of a nonlinear self-enhancement process of nanoantennas under critical laser excitation.