Metal hydride materials for solid hydrogen storage: a review

This review focuses on key aspects of the thermal decomposition of multinary or mixed hydride materials, with a particular emphasis on the rational control and chemical tuning of the strategically important thermal decomposition temperature of such hydrides, Tdec. An attempt is also made to predict the thermal stability of as-yet unknown, elusive or even unknown hydrides. The future of a particularly promising class of materials for hydrogen storage, namely the catalytically enhanced complex metal hydrides, is discussed. The predictions are supported by thermodynamics considerations, calculations derived from molecular orbital (MO) theory and backed up by simple chemical insights and intuition.

Thermal decomposition of the non-interstitial hydrides for the storage and production of hydrogen.

Hydrogen is a promising energy carrier in future energy systems. However, storage of hydrogen is a substantial challenge, especially for applications in vehicles with fuel cells that use proton-exchange membranes (PEMs). Different methods for hydrogen storage are discussed, including high-pressure and cryogenic-liquid storage, adsorptive storage on high-surface-area adsorbents, chemical storage in metal hydrides and complex hydrides, and storage in boranes. For the latter chemical solutions, reversible options and hydrolytic release of hydrogen with off-board regeneration are both possible. Reforming of liquid hydrogen-containing compounds is also a possible means of hydrogen generation. The advantages and disadvantages of the different systems are compared.

Chemical and Physical Solutions for Hydrogen Storage

Current and future potential applications for three-dimensional (3D) fibre reinforced polymer composites made by the textile processes of weaving, braiding, stitching and knitting are reviewed. 3D textile composites have a vast range of properties that are superior to traditional 2D laminates, however to date these properties have not been exploited for many applications. The scientific, technical and economic issues impeding the more widespread use of 3D textile composites are identified. Structures that have been made to demonstrate the possible uses of 3D composites are described, and these include applications in aircraft, marine craft, automobiles, civil infrastructure and medical prosthesis.

Review of applications for advanced three-dimensional fibre textile composites

Materials for hydrogen storage: current research trends and perspectives

Development of 10 kW-scale hydrogen generator using chemical hydride

Hydrogen generation by hydrolysis reaction of lithium borohydride

Development of metal hydride with high dissociation pressure

A high pressure tank has a cylindrical liner and a fiber reinforced plastic layer which covers the outer surface of the liner At least one end of the liner is separable The liner includes a cylindrical liner body and a lid An O-ring is located between the contact surfaces of the liner body and the lid in the circumferential direction Each contact surface has a seal surface which contacts the O-ring One of the liner body and the lid has a deformable portion which deforms toward the seal surfaces The structure can securely seal the separated portions of the liner when the high pressure tank is in a high pressure state

High pressure tank

A hydrogen storage apparatus that includes multiple gas storage tanks that each house a storing/adsorbing material and through the interior of which a fluid travels is provided. The gas storage apparatus 10 includes roughly cylindrical gas storage tanks 20 that house hydrogen-storing alloy. The multiple gas storage tanks 20 are disposed longitudinally parallel to each other in an ordered fashion such that roughly triangular prism-shaped empty spaces are formed between multiple adjacent hydrogen storage tanks 20. Coolant paths through which coolant flows are formed in these roughly triangular prism-shaped empty spaces. These coolant paths are thermally connected to the hydrogen-storing alloy in the gas storage tanks 20 via constituent members of the gas storage tanks 20 and via heat transfer plates 28 disposed on the gas storage tanks 20.

Masahiko Kimbara

Papers

Development of 10 kW-scale hydrogen generator using chemical hydride

Hydrogen generation by hydrolysis reaction of lithium borohydride

Development of metal hydride with high dissociation pressure

High pressure tank

Gas storage apparatus