Weyl and Dirac semimetals are three-dimensional phases of matter with gapless electronic excitations that are protected by topology and symmetry. As three-dimensional analogs of graphene, they have generated much recent interest. Deep connections exist with particle physics models of relativistic chiral fermions, and, despite their gaplessness, to solid-state topological and Chern insulators. Their characteristic electronic properties lead to protected surface states and novel responses to applied electric and magnetic fields. The theoretical foundations of these phases, their proposed realizations in solid-state systems, and recent experiments on candidate materials as well as their relation to other states of matter are reviewed.

Weyl and Dirac semimetals in three-dimensional solids

Ever since its discovery, the Berry phase has permeated through all branches of physics. Over the last three decades, it was gradually realized that the Berry phase of the electronic wave function can have a profound effect on material properties and is responsible for a spectrum of phenomena, such as ferroelectricity, orbital magnetism, various (quantum/anomalous/spin) Hall effects, and quantum charge pumping. This progress is summarized in a pedagogical manner in this review. We start with a brief summary of necessary background, followed by a detailed discussion of the Berry phase effect in a variety of solid state applications. A common thread of the review is the semiclassical formulation of electron dynamics, which is a versatile tool in the study of electron dynamics in the presence of electromagnetic fields and more general perturbations. Finally, we demonstrate a re-quantization method that converts a semiclassical theory to an effective quantum theory. It is clear that the Berry phase should be added as a basic ingredient to our understanding of basic material properties.

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Berry phase effects on electronic properties

Topological photonics is a rapidly emerging field of research in which geometrical and topological ideas are exploited to design and control the behavior of light. Drawing inspiration from the discovery of the quantum Hall effects and topological insulators in condensed matter, recent advances have shown how to engineer analogous effects also for photons, leading to remarkable phenomena such as the robust unidirectional propagation of light, which hold great promise for applications. Thanks to the flexibility and diversity of photonics systems, this field is also opening up new opportunities to realize exotic topological models and to probe and exploit topological effects in new ways. This article reviews experimental and theoretical developments in topological photonics across a wide range of experimental platforms, including photonic crystals, waveguides, metamaterials, cavities, optomechanics, silicon photonics, and circuit QED. A discussion of how changing the dimensionality and symmetries of photonics systems has allowed for the realization of different topological phases is offered, and progress in understanding the interplay of topology with non-Hermitian effects, such as dissipation, is reviewed. As an exciting perspective, topological photonics can be combined with optical nonlinearities, leading toward new collective phenomena and novel strongly correlated states of light, such as an analog of the fractional quantum Hall effect.

Topological Photonics

We present a review of experimental and theoretical studies of the anomalous Hall effect (AHE), focusing on recent developments that have provided a more complete framework for understanding this subtle phenomenon and have, in many instances, replaced controversy by clarity. Synergy between experimental and theoretical work, both playing a crucial role, has been at the heart of these advances. On the theoretical front, the adoption of Berry-phase concepts has established a link between the AHE and the topological nature of the Hall currents which originate from spin-orbit coupling. On the experimental front, new experimental studies of the AHE in transition metals, transition-metal oxides, spinels, pyrochlores, and metallic dilute magnetic semiconductors, have more clearly established systematic trends. These two developments in concert with first-principles electronic structure calculations, strongly favor the dominance of an intrinsic Berry-phase-related AHE mechanism in metallic ferromagnets with moderate conductivity. The intrinsic AHE can be expressed in terms of Berry-phase curvatures and it is therefore an intrinsic quantum mechanical property of a perfect cyrstal. An extrinsic mechanism, skew scattering from disorder, tends to dominate the AHE in highly conductive ferromagnets. We review the full modern semiclassical treatment of the AHE together with the more rigorous quantum-mechanical treatments based on the Kubo and Keldysh formalisms, taking into account multiband effects, and demonstrate the equivalence of all three linear response theories in the metallic regime. Finally we discuss outstanding issues and avenues for future investigation.

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Anomalous hall effect

The electronic and optical properties and the recent progress in applications of 2D semiconductor transition metal dichalcogenides with emphasis on strong excitonic effects, and spin- and valley-dependent properties are reviewed. Recent advances in the development of atomically thin layers of van der Waals bonded solids have opened up new possibilities for the exploration of 2D physics as well as for materials for applications. Among them, semiconductor transition metal dichalcogenides, MX2 (M = Mo, W; X = S, Se), have bandgaps in the near-infrared to the visible region, in contrast to the zero bandgap of graphene. In the monolayer limit, these materials have been shown to possess direct bandgaps, a property well suited for photonics and optoelectronics applications. Here, we review the electronic and optical properties and the recent progress in applications of 2D semiconductor transition metal dichalcogenides with emphasis on strong excitonic effects, and spin- and valley-dependent properties.

Photonics and optoelectronics of 2D semiconductor transition metal dichalcogenides

We have derived a set of semiclassical equations for electrons in magnetic Bloch bands. The velocity and energy of magnetic Bloch electrons are found to be modified by the Berry phase and magnetization. This semiclassical approach is used to study general electron transport in a dc or ac electric field. We also find a close connection between the cyclotron orbits in magnetic Bloch bands and the energy subbands in the Hofstadter spectrum. Based on this formalism, the pattern of band splitting, the distribution of Hall conductivities, and the positions of energy subbands in the Hofstadter spectrum can be understood in a simple and unified picture. \textcopyright{} 1996 The American Physical Society.

https://arxiv.org/pdf/cond-mat/9511014.pdf

Berry phase, hyperorbits, and the Hofstadter spectrum: semiclassical dynamics in magnetic Bloch bands

We develop a semiclassical theory for the dynamics of electrons in a magnetic Bloch band, where the Berry phase plays an important role. This theory, together with the Boltzmann equation, provides a framework for studying transport problems in high magnetic fields. We also derive an Onsager-like formula for the quantization of cyclotron orbits, and we find a connection between the number of orbits and Hall conductivity. This connection is employed to explain the clustering structure of the Hofstadter spectrum. The advantage of this theory is its generality and conceptual simplicity.

https://arxiv.org/pdf/cond-mat/9505021.pdf

Berry phase, hyperorbits, and the Hofstadter spectrum

Berry curvature and orbital moment of the Bloch state are two basic ingredients, in addition to the band energy, that must be included in the formulation of semiclassical dynamics of electrons in crystals, in order to give proper account of thermodynamic and transport properties to first order in the electromagnetic field. These quantities are gauge invariant and have direct physical significance as demonstrated by numerous applications in recent years. Generalization to the case of degenerate bands has also been achieved recently, with important applications in spin-dependent transport. The reader is assured that a knowledge of these ingredients of the semiclassical dynamics is also sufficient for the construction of an effective quantum theory, valid to the same order of the field, using a new quantization procedure that generalizes the venerable Peierls substitution rule. We cite the relativistic Dirac electron and the carrier in semiconductors as two prime examples to demonstrate our theory and compare with previous work on such systems. We also establish general relations between different levels of effective theories in a hierarchy.

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Berry curvature, orbital moment, and effective quantum theory of electrons in electromagnetic fields

Employing a two-band model of Weyl semimetal, the existence of the chiral magnetic effect (CME) is established within the linear-response theory. The crucial role played by the limiting procedure in deriving correct transport properties is clarified. Besides, in contrast to the prediction based on linearized effective models, the value of the CME coefficient in the uniform limit shows a nontrivial dependence on various model parameters. Even when these parameters are away from the region of the linearized models, such that the concept of chirality may not be appropriate, this effect still exists. This implies that the Berry curvature, rather than the chiral anomaly, provides a better understanding of this effect.

Ming Che Chang

Papers

Berry phase effects on electronic properties

Berry phase, hyperorbits, and the Hofstadter spectrum: semiclassical dynamics in magnetic Bloch bands

Berry phase, hyperorbits, and the Hofstadter spectrum

Berry curvature, orbital moment, and effective quantum theory of electrons in electromagnetic fields

Chiral magnetic effect in a two-band lattice model of Weyl semimetal