https://arrow.tudublin.ie/cgi/viewcontent.cgi?article=1214&context=tfschafart

Emerging technologies for the pretreatment of lignocellulosic biomass.

Insights into biochar and hydrochar production and applications: A review

An environmentally friendly, facile, and economical Fe/N co-doped carbonaceous material (Fe-N@C) was prepared by the in-situ pyrolysis of Fe/N rich Enteromorpha biomass for peroxymonosulfate activation and organic contaminants degradation. Results indicated that Enteromorpha-based catalysts prepared at high pyrolysis temperature displayed some highly graphitic nanosheets with rich nitrogen doped. The graphitic N derived from the intrinsic N in Enteromorpha showed the high correlation with the paracetamol (PCM) removal rate; this was confirmed by the Density Functional Theory (DFT) calculation, showing the high adsorption energy (ΔEads, −2.62 eV) of PMS molecular adsorbed onto the graphitic N area. A weak correlation between the PCM removal rate and adsorption capacity was also observed, revealing that the PCM catalytic reaction could be greatly accelerated after the pre-adsorption. It was interesting that the intrinsic Fe in Enteromorpha did not affect the PCM degradation, but PCM removal rate of acid treated Fe-N/C was improved as more active sites were formed after the Fe extraction by acid treatment. Both the radical pathways of O2 − and non-radical 1O2 generated in the Fe-N@C/PMS system were the primary mechanisms for the PCM degradation, which was consistent with the Fukui function values of f° and f- based on the DFT calculation. In addition, high stability of the carbon-based catalysts was observed after three runs and calcinating regeneration, which showed the promising applications for environmental remediation.

In-situ pyrolysis of Enteromorpha as carbocatalyst for catalytic removal of organic contaminants: Considering the intrinsic N/Fe in Enteromorpha and non-radical reaction

Current perspective on pretreatment technologies using lignocellulosic biomass: An emerging biorefinery concept

An overview on engineering the surface area and porosity of biochar.

Transformation and evolution mechanisms of nitrogen during algae pyrolysis were investigated in depth with exploration of N-containing products under variant temperature. Results indicated nitrogen in algae is mainly in the form of protein-N (∼90%) with some inorganic-N. At 400–600 °C, protein-N in algae cracked first with algae pyrolysis and formed pyridinic-N, pyrrolic-N, and quaternary-N in char. The content of protein-N decreased significantly, while that of pyrrolic-N and quaternary-N increased gradually with temperature increasing. Pyridinic-N and pyrrolic-N formation was due to deamination or dehydrogenation of amino acids; subsequently, some pyridinic-N converted to quaternary-N. Increasing temperature decreased amides content greatly while increased that of nitriles and N-heterocyclic compounds (pyridines, pyrroles, and indoles) in bio-oil. Amides were formed through NH3 reacting with fatty acids, that underwent dehydration to form nitriles. Besides, NH3 and HCN yields increased gradually. NH3 re...

Mingwei Xia

Papers

Transformation of Nitrogen and Evolution of N-Containing Species during Algae Pyrolysis

Insight into KOH activation mechanism during biomass pyrolysis: Chemical reactions between O-containing groups and KOH

Co-pyrolysis of lignocellulosic biomass and microalgae: Products characteristics and interaction effect.

Hierarchical porous carbon derived from wood tar using crab as the template: Performance on supercapacitor

Bamboo wastes catalytic pyrolysis with N-doped biochar catalyst for phenols products