M
Miroslav Zikmund
Researcher at Institute of Chemistry, Slovak Academy of Sciences
Publications - 1
Citations - 4
Miroslav Zikmund is an academic researcher from Institute of Chemistry, Slovak Academy of Sciences. The author has contributed to research in topics: Nucleophile & Chloride. The author has an hindex of 1, co-authored 1 publications receiving 4 citations.
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Regioselective enhancement of the nucleophilicity of the hydroxyl groups in methyl α-l-rhamnopyranoside by complexation with tin(II) chloride
TL;DR: In this paper, a tentative mechanism for complexation, and a possible model of a tin(II)chloride-methyl glycoside intermediate complex, have been established largely from analysis of methyl ethers formed on methylation of methyl α- l -rhamnopyranoside and its monomethyl ethers by diazomethane in the presence of a catalytic amount of tin (II) chloride in selected solvents.