Prediction of nonlinear viscoelastic behavior of polymeric composites using an artificial neural network

Pinus radiata wood specimens were heat-treated at 160–2108C in linseed oil and the effects of treatment on chemical composition, color, dimensional stability, and fungal resistance were examined. The degradation of hemicelluloses was the most remarkable feature, which is the principal reason for alterations in wood properties. Removal or migration of extractives, oil uptake and the accumulation of oil on the wood surface were observed. The color of heattreated wood became more uniform and darker, and its dimensional stability (i.e., anti-swelling efficiency) and fungal resistance were improved by up to 60% and 36%, respectively. The viscosity of the oil after treatment was elevated with the treatment temperature and was higher in comparison to heated oil without wood present.

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Changes in chemistry, color, dimensional stability and fungal resistance of Pinus radiata D. Don wood with oil heat-treatment

Visualization and quantification of liquid water transport in softwood by means of neutron radiography

Thermal treatment of wood using vegetable oils:a review

The low liquid permeability of refractory wood species such as Norway spruce [ Picea abies (L.) Karst.] and white Fir ( Abies alba ) is related mainly to the aspiration of bordered pits during wood drying. The resulting low permeability complicates treatments with liquid preservatives or wood modification substances. This article provides a literature review on various mechanical and biotechnological approaches that were developed for improving liquid permeability. In this context, we focus on the incubation of Norway spruce wood with a white rot fungus, Physisporinus vitreus (Pers.) P. Karst. The process is termed "bioincising" and results in a significant increase in wood permeability. This is most probably caused by the selective degradation of bordered pit membranes and simple pits of xylem ray parenchyma during the initial period of wood colonization. Subsequently, we discuss how bioincising could be a potential pretreatment method for wood preservation and selected wood modification substances. Considering that these wood modification systems require specific penetration depths for optimal performance, we discuss the capability of bioincising to enhance permeability at the required penetration depths. In this regard, we propose a terminology for better differentiation of penetration depths by liquid substances into the wood.

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A review on promising approaches for liquid permeability improvement in softwoods

Samples of pine (Pinus sylvestris) and spruce (Picea abies) were impregnated with a low-viscous epoxy resin using a vacuum process. The epoxy was cured in situ and the specimens sectioned. Deposits of the cured epoxy was then observed in the wood cavities using a scanning electron microscope. The investigation concentrated on tracing the transverse movements of a viscous liquid in the wood, and special attention was therefore given to the cross-field area between ray cells and longitudinal tracheids. A damage hypothesis is proposed based on the results obtained in the present investigation in combination with those from earlier studies on linseed oil-impregnated pine: In addition to the morphology of the bordered pits, viscous liquid flow in wood is dependent on damage that occurs during the impregnation procedure. For pine sapwood, liquid flow is enabled through disrupted window pit membranes, which divide the longitudinal tracheids and the ray parenchyma cells. A mechanism accounting for the reduced permeability of pine heartwood is believed to be deposits of higher-molecular-weight substances (extractives) in the ray parenchyma cells and on the cell walls. In spruce the thicker ray cells in combination with the smaller pits, which are connected to the longitudinal tracheids, reduce permeability considerably.

https://link.springer.com/content/pdf/10.1007%2FBF00766714.pdf

Study of the transverse liquid flow paths in pine and spruce using scanning electron microscopy

Micromechanics based modeling of nonlinear viscoplastic response of unidirectional composite

Viscoplastic strains of unidirectional continuous fiber composite (HEXCEL GF/EPprepreg system) are studied experimentally and theoretically. Creep and strainrecovery tests are used. Schapery's nonlinear viscoelastic viscoplasticconstitutive equations are used and generalized to describe inelastic behavior ofunidirectional composite under isothermal creep and strain recovery conditions. Themethodology to quantify the viscoplastic strains with respect to applied stress isproposed. Viscoplastic strains of composite are described by plastic shear strain inmaterial symmetry axis. Assumptions has been used and validated that the functiondescribing the stress and time dependence of viscoplastic strain can be presented asa product of two, time and correspondingly stress dependent, master curves.

Nonlinear viscoelastic, viscoplastic characterization of unidirectional GF/EP composite

Pine sapwood (Pinus sylvestris) was impregnated with linseed oil to three levels of uptake. The distribution of the penetrant was found by taking microdensity measurements of an impregnated sample and then using an ethanol extraction procedure to remove the linseed oil. A second set of X-ray measurements at identical locations in the same sample allowed the linseed oil to be indirectly mapped. An uneven distribution of linseed oil in the specimens with the lowest uptake (25% increase in weight) was seen as sharp gradients in the densitometry curves. With increased filling by the linseed oil, these gradients were gradually smoothed. Microstructural changes in specimens with high uptake were revealed using scanning electron microscopy. Through a combination of X-ray microdensitometry investigation and changes observed in the wood's mechanical properties and morphology, it was concluded that liquid flow during impregnation results in significant damage to the cell structure.

/pdf/measurement-of-the-uptake-of-linseed-oil-in-pine-by-the-use-og31mkf7wu.pdf

Measurement of the uptake of linseed oil in pine by the use of an X-ray microdensitometry technique

Experimental studies have been performed to obtain creep compliance functions of polypropylene (PP) and Glass Mat reinforced Thermoplastics (GMT) with PP matrix. It was found that both GMT and PP in the considered loading region may be considered as linear viscoelastic materials. The obtained viscoelastic compliance functions were successfully used to describe material behavior in the stress relaxation test. A micromechanical model based on the correspondence principle in the Laplace domain was developed to describe the viscoelastic behavior of GMT. This model considers the GMT composite with a given fiber orientation distribution function as consisting of an infinite number of unidirectional layers with orientations corresponding to this distribution function. The viscoelastic properties of the unidirectional layer are calculated using Hashin's concentric cylinder model that uses the experimentally determined viscoelastic properties of PP matrix. The predictions for GMT have been compared with experimental data. The model predicts rather good initial properties of GMT but it gives slightly less time dependence than compared to experimental data for both relaxation functions and compliance. The cause of the difference (debonding) between matrix and fiber, nonuniform fiber spatial distribution, stress concentrations etc.) is discussed.

Modris Megnis

Papers

Study of the transverse liquid flow paths in pine and spruce using scanning electron microscopy

Micromechanics based modeling of nonlinear viscoplastic response of unidirectional composite

Nonlinear viscoelastic, viscoplastic characterization of unidirectional GF/EP composite

Measurement of the uptake of linseed oil in pine by the use of an X-ray microdensitometry technique

Micromechanical modeling of viscoelastic response of GMT composite