Motohiro Akazome

TL;DR: The dichlorobis(triphenylphosphine)palladium (PdCl 2 (PPh 3 ) 1 )-tin(II) chloride (SnCl 2 ) system showed high catalytic activity for the reductive N-heterocyclization of various 2-nitrostyrene and N-(2-nitrobenzylidene)amine derivatives when employed at 100 o C for 16 h under 20 kg cm -2 of initial carbon monoxide pressure, to give the corresponding indole and 2H-indazole derivatives in

TL;DR: In this article, Tishchenko et al. present a transhydroformylation reaction for cyclohexanal, aldehyde aliphatique and heteroaromatique.

TL;DR: A combination of the palladium complex PdCl2(PPh3)2 with MoCl5 shows a high catalytic activity for the intermolecular reductive N-heterocyclization of 2-nitrobenzaldehyde or 2 -nitrophenyl ketones with formamide to give the corresponding quinazoline derivatives in moderate yields as mentioned in this paper.

TL;DR: Several ruthenium and platinum complexes smoothly catalyze the reductive N-heterocyclization of N-(2-nitrobenzoyl)amides under carbon monoxide pressure to afford the corresponding 4(3H)-quinazolinone derivatives, including some quinazolone alkaloids, in good yields.

TL;DR: It was elucidated that (R,R)-1 molecules self-assembled to form layer structures and included the sulfoxides between these layers and that the origin of the enantioselectivity based on chiral cavities was induced by conformation of the C-terminal phenyl group of the dipeptide.