Catalytic effects of nano additives on decomposition and combustion of RDX-, HMX-, and AP-based energetic compositions

A = E(l T^ admittance function, Eq. (1) sensitivity of gas phase to pressure changes specific heats of solid and gas activation energy for surface reaction E = ES/RTS enthalpy latent heat for surface reaction; Hp > 0 for exothermic s_urface reaction H = Hp/cT average mass flux fluctuation of mass flux at the surface index in the linear burning rate law, r = ap index in the surface pyrolysis law, Eq. (25) average heat release (per unit volume) in solid heat release in gas phase fluctuations of heat transfer at the average position of the surface, x = 0 fluctuations of heat release at the burning surface linear burning rate universal gas constant initial temperature of propellant, x -*• — co temperature of burning surface flame temperature average chamber temperature, x -*+ °° surface displacement, velocity functions defined in Eqs. (22) and (27) functions defined in Eqs. (22) and (27) stands for p'/p Eqs. (17-20) thermal conductivities of solid and gas stands for (ms'/m)r density of solid propellant and gas phase average density in chamber normalized temperature or a time lag dimensionless frequency parameters for the solid and gas phases; Eqs. (18) and following Eq. (34) real angular frequency mean value fluctuating value evaluated at the solid-gas interface evaluated on the gas (+) or solid ( — ) side evaluated on the gas or solid side of the mean position of the burning surface evaluated at the flame, or just downstream of the flame real part imaginary part

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A review of calculations for unsteady burning of a solid propellant.

An experimental investigation of the regression-rate characteristics of hydroxyl-terminated polybutadiene (HTPB) solid fuel burning with oxygen was conducted using a windowed, slab-geometry hybrid rocket motor. A real-time, x-ray radiography system was used to obtain instantaneous solid-fuel regression rate data at many axial locations. Fuel temperature measurements were made using an array of 25- πm e ne-wire embedded thermocouples. The regression rates displayed a strong dependence on axial location near the motor head-end. At lower mass e ux levels, thermal radiation was found to signie cantly ine uence the regression rates. The regression rates werealso affected by theadditionofactivated aluminum powder.A 20%by weightaddition of activated aluminum to HTPB increased the fuel mass e ux by 70% over that of pure HTPB. Correlations were developed to relate the regression rate to operating conditions and port geometry for both pure HTPB and for HTPB loaded with certain fractions of activated aluminum. Thermocouple measurements indicated that the fuel surface temperatures for pureHTPBwerebetween930 and1190 K.TheHTPBactivationenergywasestimatedat11.5 kcal/mole,suggesting that the overall regression process is governed by physical desorption of high-molecular weight fragments from the fuel surface.

Regression Rate Behavior of Hybrid Rocket Solid Fuels

This volume brings together international scientists in the field of solid rocket propulsion. Thirty-nine papers present in-depth coverage on a wide range of topics including: advanced materials and non-traditional formulations; the chemical aspects of organic and inorganic components in relation to decomposition mechanisms, kinetics, combustion and modelling; safety issues, hazards and explosive characteristics; and experimental and computational interior ballistics research, including chemical information and the physics of the complex flow field.

Solid propellant chemistry, combustion, and motor interior ballistics

Thermal decomposition of energetic materials 3. A high-rate, in situ, FTIR study of the thermolysis of RDX and HMX with pressure and heating rate as variables☆

This paper presents an analytical model for the combustion of HMX that is based upon the work of Ben Reuven and Caveny. Two alternative schemes for the combustion chemistry are proposed. Simplifying assumptions are made to achieve a closed-form solution for the condensed phase and three model versions differing in complexity for the gas phase. The paper emphasizes one of the chemistries in the calculated results presented. It is concluded that the combustion is controlled by vapor phase decomposition and that it would be difficult to achieve large burning rate increases by catalysis. For this particular problem, it is permissible to neglect mass diffusion in the conservation equations in the interests of computational convenience, but energy diffusion cannot be neglected except for limited purposes.

Model and chemistry of HMX combustion

Passage en revue des mecanismes qui affectent la sensibilite a la temperature: les mecanismes directs traites dans les modeles analytiques, les aspects non ideaux du processus de combustion, la derive des mecanismes de controle

Mechanisms and models of solid-propellant burn rate temperature sensitivity - A review

The paper presents theoretical models developed to account for the heterogeneity of composite propellants in expressing the pressure-coupled combustion response function. It is noted that the model of Lengelle and Williams (1968) furnishes a viable basis to explain the effects of heterogeneity.

Response function theories that account for size distribution effects - A review

A mechanism involving compositional fluctuations at certain frequencies is examined by which the heterogeneity of a composite solid propellant may contribute directly to the combustion response function of combustion instability theory. A combustion model appropriate to ammonium perchlorate (AP) is used to derive the combustion response to compositional fluctuations, and the properties of the combustion response are discussed in terms of the theoretical results obtained. The concentration exponent, i.e., the dependence of the burn rate on AP concentration, is found to be a signficant combustion parameter and to have a tremendous range of variability. It is suggested that the combustion response to compositional fluctuations may be a dominating factor in driving combustion instability.

Combustion response to compositional fluctuations

This paper presents several improvements to the BDP model of steady-state burning of AP composite solid propellants. The Price-Boggs-Derr model of AP monopropellant burning is incorporated to represent the AP. A separate energy equation is written for the binder to permit a different surface temperature from the AP; this includes an analysis of the sharing of primary diffusion flame energy, and correction of a BDP model inconsistency in treating the binder regression rate. A method for assembling component contributions to calculate the burning rates of multimodal propellants is also presented. Results are shown in the form of representative burning rate curves, comparisons with data, and calculated internal details of interest. Ideas for future work are discussed in an Appendix.

Norman S. Cohen

Papers

Model and chemistry of HMX combustion

Mechanisms and models of solid-propellant burn rate temperature sensitivity - A review

Response function theories that account for size distribution effects - A review

Combustion response to compositional fluctuations

An improved model for the combustion of AP composite propellants