This invention relates to a formulation with the addition of low density additives of volcanic ash, hollow ceramic microspheres or a combination of microspheres and volcanic ash or other low density additives into cementitious cellulose fiber reinforced building materials. This formulation is advantageously lightweight or low density compared as compared to current fiber cement products without the increased moisture expansion and freeze-thaw degradation usually associated with the addition of lightweight inorganic materials to fiber cement mixes. The low density additives also give the material improved thermal dimensional stability.

Fiber cement building materials with low density additives

This invention generally relates to a new method and apparatus for the fast pyrolysis of carbonaceous materials involving rapid mixing, high heat transfer rates, precisely controlled short uniform residence times and rapid primary product quench in an upflow, entrained-bed, transport reactor with heat carrier solids recirculation. A carbonaceous feedstock, a non-oxidative transport gas and inorganic particulate heat supplying material are rapidly mixed in a reactor base section, then transported upward through an entrained-bed tubular reactor. A cyclonic hot solids recirculation system separates the solids from the non-condensible gases and primary product vapors and returns them to the mixer. Product vapors are rapidly quenched to provide maximum yields of liquids, petrochemicals, high value gases and selected valuable chemicals.

Apparatus for a circulating bed transport fast pyrolysis reactor system

Method and apparatus for a circulating bed transport fast pyrolysis reactor system

A self-sustaining system for converting organic waste feedstreams into usable solid and gas end products includes a plurality of interconnected retorts, an apparatus for flash pyrolyzing the feedstream to form intermediate gas and solid products, a source for introducing a water spray to refine and cool the intermediate products, a device for separating the gas product from the solid product and a device for regenerating, and thereby further refining, the solid product. In a self-sustaining process, wastes which would otherwise be landfilled are converted to an activated carbon product and a combustible gas mixture of hydrogen, carbon monoxide, and lower hydrocarbons.

Pyrolytic conversion of organic feedstock and waste

A rotary, continuous pyrolytic conversion system converts solid hydrocarbons into gases, liquid hydrocarbons and char by pyrolyzing feed stocks including: plastic waste, tires and plastic from automobile shredding operations; containers and trays of styrofoam and other plastic materials such as used in "fast food" restaurants; rubber; leather; tires; garbage; sewage sludge; coal; oil shale; broken asphalt and the like. These materials are preferably shredded and kinds thereof having different melting points are mixed to facilitate movement of the feed stock through the converter without clogging. Preferably, the materials are baled and injected into the converter where they are severed as they are injected. The materials are fed by gravity from the input end of a converter drum to the discharge end thereof; the input end being elevated above the discharge end. The converter drum is contained within an outer drum which is in substantially air-tight relationship with the injector for the bales and with a discharge chute for the solid products of pyrolysis. A casing around the outer stationary drum defines an oven chamber which is heated by combustion products, from a burner providing a heat source, which circulate in heat exchange relationship with a matrix of fins extending into the oven from the stationary outer drum. A rod extends into the injection end of the converter drum for supporting scrapers against the inner periphery of the converter drum. A crusher bar is carried in the drum at the discharge end thereof and crushes the solid products which consists of char (mostly carbon black), metals and other non-organic materials. A chute containing water receives the pulverized discharge product and balances the pressure in the converter to maintain an air-tight seal therein. A second pyrolysis reactor may receive the solid pyrolysis products and be operative at higher temperature than the first converter to destroy chlorinated hydrocarbons. To assist in such destruction, lime may be injected into the first converter. A plurality of converters may be operated in parallel and utilize common equipment for cleaning the product gases released upon pyrolysis and to supply them to the burners of each of the reactors. Flue gases from the oven chambers of one of the plurality of converters may be supplied to the burner of the next converter for preheating gases for combustion therein.

Pyrolytic conversion system

In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue. Apparatus useful for practicing this process are disclosed.

Pyrolysis of carbonaceous materials with solvent quench recovery

In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source over an overflow weir to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue and separating out the fines.

Pyrolysis with cyclone burner

In a continuous process for recovery of values contained in a solid carbonaceous material, the carbonaceous material is comminuted and then subjected to flash pyrolysis in the presence of a particulate heat source fed over an overflow weir to form a pyrolysis product stream containing a carbon containing solid residue and volatilized hydrocarbons. After the carbon containing solid residue is separated from the pyrolysis product stream, values are obtained by condensing volatilized hydrocarbons. The particulate source of heat is formed by oxidizing carbon in the solid residue.

Pyrolysis with staged recovery

A solid carbonaceous material is pyrolyzed in a descending flow pyrolysis reactor in the presence of a particulate source of heat to yield a particulate carbon containing solid residue. The particulate source of heat is obtained by educting with a gaseous source of oxygen the particulate carbon containing solid residue from a fluidized bed into a first combustion zone coupled to a second combustion zone. A source of oxygen is introduced into the second combustion zone to oxidize carbon monoxide formed in the first combustion zone to heat the solid residue to the temperature of the particulate source of heat.

Pyrolysis reactor and fluidized bed combustion chamber

To prevent plugging in a pyrolysis operation where an agglomerative coal in a nondeleteriously reactive carrier gas is injected as a turbulent jet from an opening into an elongate pyrolysis reactor, the coal is comminuted to a size where the particles under operating conditions will detackify prior to contact with internal reactor surfaces while a secondary flow of fluid is introduced along the peripheral inner surface of the reactor to prevent backflow of the coal particles. The pyrolysis operation is depicted by two equations which enable preselection of conditions which insure prevention of reactor plugging.

Norman W. Green

Papers

Pyrolysis of carbonaceous materials with solvent quench recovery

Pyrolysis with cyclone burner

Pyrolysis with staged recovery

Pyrolysis reactor and fluidized bed combustion chamber

Method for preventing plugging in the pyrolysis of agglomerative coals