Lithium metal batteries (LMBs) are among the most promising candidates of high-energy-density devices for advanced energy storage. However, the growth of dendrites greatly hinders the practical applications of LMBs in portable electronics and electric vehicles. Constructing stable and efficient solid electrolyte interphase (SEI) is among the most effective strategies to inhibit the dendrite growth and thus to achieve a superior cycling performance. In this review, the mechanisms of SEI formation and models of SEI structure are briefly summarized. The analysis methods to probe the surface chemistry, surface morphology, electrochemical property, dynamic characteristics of SEI layer are emphasized. The critical factors affecting the SEI formation, such as electrolyte component, temperature, current density, are comprehensively debated. The efficient methods to modify SEI layer with the introduction of new electrolyte system and additives, ex-situ-formed protective layer, as well as electrode design, are summarized. Although these works afford new insights into SEI research, robust and precise routes for SEI modification with well-designed structure, as well as understanding of the connection between structure and electrochemical performance, is still inadequate. A multidisciplinary approach is highly required to enable the formation of robust SEI for highly efficient energy storage systems.

https://onlinelibrary.wiley.com/doi/pdf/10.1002/advs.201500213

A Review of Solid Electrolyte Interphases on Lithium Metal Anode.

The ever-increasing demand for storing renewable energy sources calls for novel battery technologies that are of sustainably low levelized energy cost. Research into battery chemistry has evolved to a stage where a plethora of choices based on earth-abundant elements can be compared during their development. One of the emerging candidates is the nonaqueous potassium-ion battery. K-ion’s unique properties as a charge carrier have aroused intense interest in exploring high-performing cathode and anode materials for this battery. Rapid progress has been made, where leading candidates of electrodes have been proposed, i.e., hard carbon as anode and Prussian white analogues as cathode. In this new battery technology’s infancy, it is our opinion that the focus should be given to potentially scalable, inexpensive electrode materials and the understanding of their cycle-life-property correlations. It may be the ultralong cycle life that differentiates potassium-ion batteries from sodium-ion batteries in the futur...

Emerging Non-Aqueous Potassium-Ion Batteries: Challenges and Opportunities

Advancements and Challenges in Potassium Ion Batteries: A Comprehensive Review

J-YH and S-TM contributed equally to this work This work was supported by the Human Resources Development program (Grant No 20154010200840) from a Korea Institute of Energy Technology Evaluation and Planning (KETEP) grant, funded by the Ministry of Trade, Industry and Energy of the Korean government, and supported by the Global Frontier RaD program (Grant No 2013M3A6B1078875) of the Center for Hybrid Interface Materials (HIM) of the Ministry of Science and ICT

Recent Progress in Rechargeable Potassium Batteries

Suppressing dendrite formation at lithium metal anodes during cycling is critical for the implementation of future lithium metal-based battery technology. Here we report that it can be achieved via the facile process of immersing the electrodes in ionic liquid electrolytes for a period of time before battery assembly. This creates a durable and lithium ion-permeable solid-electrolyte interphase that allows safe charge-discharge cycling of commercially applicable Li|electrolyte|LiFePO4 batteries for 1,000 cycles with Coulombic efficiencies >99.5%. The tailored solid-electrolyte interphase is prepared using a variety of electrolytes based on the N-propyl-N-methylpyrrolidinium bis(fluorosulfonyl)imide room temperature ionic liquid containing lithium salts. The formation is both time- and lithium salt-dependant, showing dynamic morphology changes, which when optimized prevent dendrite formation and consumption of electrolyte during cycling. This work illustrates that a simple, effective and industrially applicable lithium metal pretreatment process results in a commercially viable cycle life for a lithium metal battery.

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Stabilizing lithium metal using ionic liquids for long-lived batteries

Corrosion/passivation of aluminum current collector in bis(fluorosulfonyl)imide-based ionic liquid for lithium-ion batteries

Prediction of uniaxial tensile flow using finite element-based indentation and optimized artificial neural networks

An electrolyte for a redox flow battery and a redox flow battery including the electrolyte, the electrolyte including a metal-ligand coordination compound as a cation and an anion containing at least four atoms linked to each other by a straight chain in a certain direction

Oh Min Kwon

Papers

Corrosion/passivation of aluminum current collector in bis(fluorosulfonyl)imide-based ionic liquid for lithium-ion batteries

Prediction of uniaxial tensile flow using finite element-based indentation and optimized artificial neural networks

Electrolyte for redox flow battery and redox flow battery including the same

Novel Pyrrolinium-based Ionic Liquids for Lithium Ion Batteries: Effect of the Cation on Physicochemical and Electrochemical Properties

Highly Soluble Tris(2,2 '-bipyridine) Metal Bis(trifluoromethanesulfonyl)imide Complexes for High Energy Organic Redox Flow Batteries