P
Paolo Uguagliati
Researcher at Ca' Foscari University of Venice
Publications - 106
Citations - 1678
Paolo Uguagliati is an academic researcher from Ca' Foscari University of Venice. The author has contributed to research in topics: Palladium & Ligand. The author has an hindex of 24, co-authored 106 publications receiving 1649 citations. Previous affiliations of Paolo Uguagliati include University of Padua & University of Bologna.
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Solution Behavior and X-ray Structure of Cationic Allylpalladium(II) Complexes with Iminophosphine Ligands. Kinetics and Mechanism of Allyl Amination by Secondary Amines
Bruno Crociani,Simonetta Antonaroli,Giuliano Bandoli,Luciano Canovese,Fabiano Visentin,Paolo Uguagliati +5 more
TL;DR: The solution behavior of the cationic complexes [Pd(η3-allyl)(P−N)]+ (Pd = o-(PPh2)C6H4CHNR (R = C6H 4OMe-4, Me, CMe3, (R)-bornyl); allyl = propenyl (1a−4a) and 3-methyl-2-butenyl(1b−4b)) consists essentially of three dynamic processes: a very fast conformational change of the P−N chelate ring
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Carbonylation of ethanol promoted by palladium chloride
TL;DR: In this paper, the reaction of ethanol with carbon monoxide at atmospheric pressure and mild temperatures in the presence of palladium chloride and lithium chloride produces ethyl chlorocarbonate, ethyl acetate, palladium metal, and an unidentified compound.
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Synthesis, characterization and X-ray structural determination of palladium(0)–olefin complexes containing pyridin-thioethers as ancillary ligands. Equilibria and rates of olefin and ligand exchange
TL;DR: In this paper, the synthesis of Pd(0)-olefin complexes with pyridin-thioether ligands R′NSR is reported. X-ray structure determinations of selected species are described.
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Palladium(II) allyl complexes with nitrogen–sulfur bidentate ligands. Substituent effects in the mechanism of allyl amination
TL;DR: In this paper, the reactivity of palladium(II) allyl complexes containing the nitrogen-sulfur bidentate ligand N-SR was studied in CHCl3 in the presence of activated olefin fumaronitrile (fn).
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Remarkable, Sterically Induced Rate Enhancement in the Insertion of Allenes into Palladium-Methyl Bonds
TL;DR: In this paper, the rate of insertion of methyl-substituted allenes into the Pd−Me bond in chelate pyridine−thioether complexes [PdCl(Me)(R‘N-SR)] (R N-SR = 6-R'-C5H3N-2-CH2SR) to give 2-methylallyl derivatives was investigated.