A process for producing new crystalline titanium molecular sieve zeolite compositions having a pore size of about 3-5 Angstrom Units is disclosed.

Preparation of small-pored crystalline titanium molecular sieve zeolites

Disclosed are liquid automatic dishwashing detergent compositions containing an insoluble inorganic zinc salt useful for inhibition of glassware corrosion in the dishwasher. These compositions are particularly desirable because use of them in the dishwasher does not result in precipitation of insolubles on the dishware or dishwasher parts.

Liquid automatic dishwashing compositions compounds providing glassware protection

This invention relates to the synthesis of large pore composite molecular sieves and the synthetic large pore composite molecular sieves so produced. The molecular sieves of the invention have the same general utilities of the comparable molecular sieves of the prior art but have been found to be superior catalysts and absorbents. This invention relates to a hydrothermal synthesis of large pore molecular sieves from nutrients, at least one of which contains an amorphous framework-structure, and which framework-structure is essentially retained in the synthetic molecular sieve. This invention stems from a discovery that the intrinsic porosity characteristics of a nutrient that possesses an amorphous cation oxide-framework can be substantially retained in the final molecular sieve containing product formed by a hydrothermal process by carefully controlling the conditions under which the hydrothermal process is conducted. For example, the invention contemplates retention of the particle size in a final molecular sieve-containing product that corresponds with that of an amorphous cation oxide-framework nutrient used in its manufacture. This invention drives the selection of process conditions to achieve one or more of macro and meso porosity ("large pore composite porosity") in the final molecular sieve product as a direct product of the hydrothermal reaction producing the molecular sieve. The invention allows the production of a molecular sieve that is in in situ incorporated in the framework morphology of a solid cation oxide-framework used in the molecular sieve's manufacture. This invention relates to the synthesis of large pore composite molecular sieves and the synthetic large pore composite molecular sieves so produced. The molecular sieves of the invention have the same general utilities of the comparable molecular sieves of the prior art but have been found to be superior catalysts and absorbents. This invention relates to a hydrothermal synthesis of large pore molecular sieves from nutrients, at least one of which contains an amorphous framework-structure, and which framework-structure is essentially retained in the synthetic molecular sieve. This invention stems from a discovery that the intrinsic porosity characteristics of a nutrient that possesses an amorphous cation oxide-framework can be substantially retained in the final molecular sieve containing product formed by a hydrothermal process by carefully controlling the conditions under which the hydrothermal process is conducted. For example, the invention contemplates retention of the particle size in a final molecular sieve-containing product that corresponds with that of an amorphous cation oxide-framework nutrient used in its manufacture. This invention drives the selection of process conditions to achieve one or more of macro and meso porosity ("large pore composite porosity") in the final molecular sieve product as a direct product of the hydrothermal reaction producing the molecular sieve. The invention allows the production of a molecular sieve that is in in situ incorporated in the framework morphology of a solid cation oxide-framework used in the molecular sieve's manufacture.

Method for making molecular sieves and novel molecular sieve compositions

Disclosed are granular automatic dishwashing detergent compositions containing an insoluble inorganic zinc salt useful for inhibition of glassware corrosion in the dishwasher. These compositions are particularly desirable because use of them in the dishwasher does not result in precipitation of zinc insolubles on the dishware or dishwasher parts.

Granular automatic dishwasher detergent composition providing glassware protection containing insoluble zinc compound

Molecular sieve compositions are prepared by extracting aluminum and substituting chromium and/or tin for extracted aluminum to give molecular sieve products containing framework chromium and/or tin atoms. The process of preparing the chromium and/or tin-containing molecular sieves involves contacting a starting molecular sieve with a solution or slurry of at least one of a fluoro salt of chromium or a fluoro salt of tin under effective process conditions to provide for aluminum extraction and substitution of chromium and/or tin.

Substitution of cr and/or sn in place of a1 in the framework of molecular sieve via treatment with fluoride salts

Sodium zinco/stanno/titano-silicate is synthesized by mixing a concentrated aqueous sodium zincate, stannate or titanate solution with a source of silica (e.g. powdered glass or sodium metasilicate solution) in the ratio 60 g sodium silicate to sodium zincate equivalent to 8.1 g zinc oxide, keeping the temperature at 40° C. for 1/2 hour, diluting threefold with water of 20° C., allowing a precipitate to form overnight, and filtering and drying the residue at 110° C. The resulting sodium zincosilicate may be used in its own right as a water softener or may be converted by cation exchange into any other desired zincosilicate.

Method of synthesizing zincosilicate or stannosilicate or titanosilicate material

Sodium zinco/stanno/titano-silicate is synthesised by mixing a concentrated aqueous sodium zincate (stannate, titanate) solution with a source of silica (e.g. powdered glass or sodium metasilicate solution) in the ratio 60g sodium silicate to sodium zincate equivalent to 8.1g zinc oxide, keeping the temperature at 40°C for hour, diluting threefold with water of 20°C, allowing a precipitate to form overnight, and filtering and drying the residue at 110°C. The resulting sodium zincosilicate may be used in its own right as a water softener or may be converted by cation exchange into any other desired zincosilicate.

Method of synthesising sodium zincosilicate and stannosilicate and ion-exchanged products thereof,detergent formulations containing the sodium zincosilicate or stannosilicate products and catalysts or catalyst supports containing the ion-exchanged products

Patrick Mcanespie

Papers

Method of synthesizing zincosilicate or stannosilicate or titanosilicate material

Method of synthesising sodium zincosilicate and stannosilicate and ion-exchanged products thereof,detergent formulations containing the sodium zincosilicate or stannosilicate products and catalysts or catalyst supports containing the ion-exchanged products