Metamaterials are artificially fabricated materials that allow for the control of light and acoustic waves in a manner that is not possible in nature. This Review covers the recent developments in the study of so-called metasurfaces, which offer the possibility of controlling light with ultrathin, planar optical components. Conventional optical components such as lenses, waveplates and holograms rely on light propagation over distances much larger than the wavelength to shape wavefronts. In this way substantial changes of the amplitude, phase or polarization of light waves are gradually accumulated along the optical path. This Review focuses on recent developments on flat, ultrathin optical components dubbed 'metasurfaces' that produce abrupt changes over the scale of the free-space wavelength in the phase, amplitude and/or polarization of a light beam. Metasurfaces are generally created by assembling arrays of miniature, anisotropic light scatterers (that is, resonators such as optical antennas). The spacing between antennas and their dimensions are much smaller than the wavelength. As a result the metasurfaces, on account of Huygens principle, are able to mould optical wavefronts into arbitrary shapes with subwavelength resolution by introducing spatial variations in the optical response of the light scatterers. Such gradient metasurfaces go beyond the well-established technology of frequency selective surfaces made of periodic structures and are extending to new spectral regions the functionalities of conventional microwave and millimetre-wave transmit-arrays and reflect-arrays. Metasurfaces can also be created by using ultrathin films of materials with large optical losses. By using the controllable abrupt phase shifts associated with reflection or transmission of light waves at the interface between lossy materials, such metasurfaces operate like optically thin cavities that strongly modify the light spectrum. Technology opportunities in various spectral regions and their potential advantages in replacing existing optical components are discussed.

Flat Optics With Designer Metasurfaces

We present single-molecule, real-time sequencing data obtained from a DNA polymerase performing uninterrupted template-directed synthesis using four distinguishable fluorescently labeled deoxyribonucleoside triphosphates (dNTPs). We detected the temporal order of their enzymatic incorporation into a growing DNA strand with zero-mode waveguide nanostructure arrays, which provide optical observation volume confinement and enable parallel, simultaneous detection of thousands of single-molecule sequencing reactions. Conjugation of fluorophores to the terminal phosphate moiety of the dNTPs allows continuous observation of DNA synthesis over thousands of bases without steric hindrance. The data report directly on polymerase dynamics, revealing distinct polymerization states and pause sites corresponding to DNA secondary structure. Sequence data were aligned with the known reference sequence to assay biophysical parameters of polymerization for each template position. Consensus sequences were generated from the single-molecule reads at 15-fold coverage, showing a median accuracy of 99.3%, with no systematic error beyond fluorophore-dependent error rates.

/pdf/real-time-dna-sequencing-from-single-polymerase-molecules-3o0n2kc430.pdf

Real-Time DNA Sequencing from Single Polymerase Molecules

Pacific Biosciences has developed a method for real-time sequencing of single DNA molecules (Eid et al., 2009), with intrinsic sequencing rates of several bases per second and read lengths into the kilobase range. Conceptually, this sequencing approach is based on eavesdropping on the activity of DNA polymerase carrying out template-directed DNA polymerization. Performed in a highly parallel operational mode, sequential base additions catalyzed by each polymerase are detected with terminal phosphate-linked, fluorescence-labeled nucleotides. This chapter will first outline the principle of this single-molecule, real-time (SMRT) DNA sequencing method, followed by descriptions of its underlying components and typical sequencing run conditions. Two examples are provided which illustrate that, in addition to the DNA sequence, the dynamics of DNA polymerization from each enzyme molecules is directly accessible: the determination of base-specific kinetic parameters from single-molecule sequencing reads, and the characterization of DNA synthesis rate heterogeneities.

Real-time DNA sequencing from single polymerase molecules.

Multi-wavelength light is directed to an optic including a substrate and achromatic metasurface optical components deposited on a surface of the substrate. The achromatic metasurface optical components comprise a pattern of dielectric resonators. The dielectric resonators have nonperiodic gap distances between adjacent dielectric resonators; and each dielectric resonator has a width, w, that is distinct from the width of other dielectric resonators. A plurality of wavelengths of interest selected from the wavelengths of the multi-wavelength light are deflected with the achromatic metasurface optical components at a shared angle or to or from a focal point at a shared focal length.

/pdf/achromatic-metasurface-optical-components-by-dispersive-47jfe0x7a1.pdf

Achromatic Metasurface Optical Components by Dispersive Phase Compensation

BACKGROUND Future high-performance portable and wearable optical devices and systems with small footprints and low weights will require components with small form factors and enhanced functionality. Planar components based on diffractive optics (e.g., gratings, Fresnel lenses) and thin-film optics (e.g., dielectric filters, Bragg reflectors) have been around for decades; however, their limited functionality and difficulty of integration have been key incentives to search for better alternatives. Owing to its potential for vertical integration and marked design flexibility, metasurface-based flat optics provides a rare opportunity to overcome these challenges. The building blocks (BBs) of metasurfaces are subwavelength-spaced scatterers. By suitably adjusting their shape, size, position, and orientation with high spatial resolution, one can control the basic properties of light (phase, amplitude, polarization) and thus engineer its wavefront at will. This possibility greatly expands the frontiers of optical design by enabling multifunctional components with attendant reduction of thickness, size, and complexity. ADVANCES Recent progress in fabrication techniques and in the theory and design of metasurfaces holds promise for this new optical platform (metaoptics) to replace or complement conventional components in many applications. One major advance has been the migration to all-dielectric metasurfaces. Here, we discuss the key advantages of using dielectric phase-shifting elements with low optical loss and strong light confinement in the visible and near-infrared regions as BBs of flat lenses (metalenses). High–numerical aperture metalenses that are free of spherical aberrations have been implemented to achieve diffraction-limited focusing with subwavelength resolution, without requiring the complex shapes of aspherical lenses. Achromatic metalenses at discrete wavelengths and over a bandwidth have been realized by dispersion engineering of the phase shifters. By suitably adjusting the geometrical parameters of the latter, one can impart polarization- and wavelength-dependent phases to realize multifunctional metalenses with only one ultrathin layer. For example, polarization-sensitive flat lenses for chiral imaging and circular dichroism spectroscopy with high resolution have been realized, and off-axis metalenses with large engineered angular dispersion have been used to demonstrate miniature spectrometers. The fabrication of metalenses is straightforward and often requires one-step lithography, which can be based on high-throughput techniques such as deep-ultraviolet and nanoimprint lithography. OUTLOOK In the near future, the ability to fabricate metalenses and other metaoptical components with a planar process using the same lithographic tools for manufacturing integrated circuits (ICs) will have far-reaching implications. We envision that camera modules widely employed in cell phones, laptops, and myriad applications will become thinner and easier to optically align and package, with metalenses and the complementary metal-oxide semiconductor–compatible sensor manufactured by the same foundries. The unprecedented design freedom of metalenses and other metasurface optical components will greatly expand the range of applications of micro-optics and integrated optics. We foresee a rapidly increasing density of nanoscale optical elements on metasurface-based chips, with attendant marked increases in performance and number of functionalities. Such digital optics will probably follow a Moore-like law, similar to that governing the scaling of ICs, leading to a wide range of high-volume applications.

http://science.sciencemag.org/content/sci/358/6367/eaam8100.full.pdf

Metalenses: Versatile multifunctional photonic components

By focusing light with a sphere several wavelengths in diameter, we can obtain a photonic nanojet [Opt. Express13, 526 (2005) ]: if light is focused on the surface of the sphere, the width of the beam stays smaller than the wavelength along a distance of propagation of approximately two wavelengths and reaches a high intensity. We use the rigorous Mie theory to analyze the basic properties of the photonic jet in the general three-dimensional polarized case. This fast algorithm allows us to determine the influence of the radius and the refractive index of the sphere on the photonic jet. The polarization response is also studied. We observe that high-intensity concentrations and subwavelength focusing are two different effects. Their basic properties are analyzed, and explanations are proposed.

Properties of a three-dimensional photonic jet

We report for the first time on the experimental response of a Surface Plasmon Resonance fiber optic sensor based on wavelength modulation for hydrogen sensing. This approach of measuring the hydrogen concentration makes the sensor insensitive to intensity fluctuations. The intrinsic fiber sensor developed provides remote sensing and enables the possibility of multi-points sensing. The sensor consists of a multilayer of 35 nm Au / 180 nm SiO2/ Pd deposited on a step- index multimode fiber core. The sensitivity and selectivity of the sensor are optimal at a Pd thickness of 3.75 nm. The sensor is sensitive to a hydrogen concentration ranging between 0.5 and 4% H2 in Ar, with a response time less than 15 s.

/pdf/a-reliable-sensitive-and-fast-optical-fiber-hydrogen-sensor-175pm3w8wz.pdf

A reliable, sensitive and fast optical fiber hydrogen sensor based on surface plasmon resonance.

A new design of a fiber optic Surface Plasmon Resonance (SPR) sensor using Palladium as a sensitive layer for hydrogen detection is presented. In this approach, a transducer layer is deposited on the outside of a multimode fiber, after removing the optical cladding. The transducer layer is a multilayer stack made of a Silver, a Silica and a Palladium layer. The spectral modulation of the light transmitted by the fiber allows to detect the presence of hydrogen in the environment. The sensor is only sensitive to the Transverse Magnetic polarized light and the Traverse Electric polarized light can be used therefore as a reference signal. A more reliable response is expected for the fiber SPR hydrogen sensor based on spectral modulation instead of on intensity modulation. The multilayer thickness defines the sensor performance. The silica thickness tunes the resonant wavelength, whereas the Silver and Palladium thickness determine the sensor sensitivity. In an optimal configuration (NA = 0.22, 100 μm core radius and transducer length = 1 cm), the resonant wavelength is shifted over 17.6 nm at a concentration of 4% Hydrogen in Argon for the case of the 35 nm Silver/ 100 nm Silica/ 3 nm palladium multilayer.

/pdf/fiber-optic-surface-plasmon-resonance-sensor-based-on-15m29p3ca1.pdf

Fiber optic Surface Plasmon Resonance sensor based on wavelength modulation for hydrogen sensing

Applied Digital Optics

Introduction: From Diffraction to Diffractive Optics. Design and Simulation of Diffractive Optical Elements. DOE Fabrication and Replication Techniques. CAD/CAM Tools for DOEs. DOE Fabrication Tolerancing Analysis. DOE Mask Layout Generation. System-Oriented DOE Designs: Examples. Conclusion. Index.

Patrick Meyrueis

Papers

Properties of a three-dimensional photonic jet

A reliable, sensitive and fast optical fiber hydrogen sensor based on surface plasmon resonance.

Fiber optic Surface Plasmon Resonance sensor based on wavelength modulation for hydrogen sensing

Applied Digital Optics

Digital Diffractive Optics: An Introduction to Planar Diffractive Optics and Related Technology