Use of an N-phenylcarbamate of the formula: ##STR1## as a fungicidal agent against phytophatogenic fungi, particularly strains which are resistant to benzimidazole thiophanate fungicides and/or cyclic imide fungicides.

Fungicidal n-phenylcarbamates

The present invention is concerned with compounds of formula (I) wherein Ar is a mono- or bicyclic aromatic group op-tionally containing one or two heteroatoms independently selected from nitrogen, oxigen and sulphur, said group being optional-ly substituted by one or more atoms or groups independently selected from halogen, vitro, amino, -NRR1 where R and R1 are independently selected from hydrogen, C1-8 alkyl and C1-8 alkanoyl, cyano, carboxyalkoxy, alkoxycarbonylalkoxy, C1-8 al-kyl (including cycloalkyl and cycloalkylalkyl), C1-8 alkoxy (including cycloalkoxy and cycloalkylalkoxy), C1-8 thioalkyl, said alkyl, alkoxy and/or thioalkyl groups) being optionally substituted by one or more halogen atoms, aryl, aryloxy, aralkyl and aralkyloxy, said aryl, aryloxy, aralkyl and/or aralkyloxy group(s) being optionally substituted by one or more atoms or groups independently selected from halogen, alkyl, alkoxy, alkanoyl, hydroxyalkyl, perfluoroalkyl, perfluoroalkoxy, carbox-yalkoxy, alkoxycarbonylalkoxy, and C3-8 polyether groups containing from one to three oxygen atoms; D is -CH2-, -NH-, or -O-; E is (a) or (b); G is hydrogen, C1-12 straight, branched, or cyclic alkyl, or aralkyl, said aralkyl group being optionally substituted by one or more atoms or groups independently selected from halogen, amino, N-(C1-6 alkyl)amino, N,N-di(C1-6 alkyl)amino, C1-6 alkyl and C1-6 alkoxy, or a C3-8 polyether group containing one to three oxygen atoms; J is a bond or C1-6 straight or branched alkylene; n is an integer of from O to 10; R and R1 are as hereinbefore defined; and K is -CH2OH, -CHO, -CONHCH2CONH2, .cndot.CONH(C1-6 alkyl), -OC(C1-4 alkyl)2OCO heteroaryl, -CO2R2 where R2 is hydrogen, C1-8 al-kyl, aryl, heteroaryl, aralkyl, heteroaralkyl, or a C3-8 polyether group containing from one to three oxygen atoms, or -CON-HAr' where Ar' is phenyl optionally substituted by one or more atoms or groups selected from fluorine, nitro, -NRR1 where R and R1 are as hereinbefore defined, C1-6 alkyl and C1-6 alkoxy, said alkyl and/or alkoxy group(s) being optionally substi-tuted at the terminal carbon by -CO2R3 where R3 is C1-6 alkyl; and their physiologically functional derivatives, with pro-cesses for their preparation, with medicaments containing them and with their use as therapeutic agents, particularly in the prophylaxis and treatment of atherosclerosis.

Anti-atherosclerotic aryl compounds

Herbicidally active thiocarbamates are employed in combination with organophosphorothioates and -dithioates and -phosphonothioates, -dithioates and -trithioates, the latter in sufficient quantity to prevent soil degradation of the former As a result, the herbicidal effectiveness of the thiocarbamate is significantly enhanced and prolonged, rendering a single application of the herbicide effective over a longer period of time Such herbicidal compositions can optionally contain a non-phytotoxic antidotally effective amount of an amide of haloalkanoic or dihaloalkanoic acid

Herbicide compositions of extended soil life

Environmentally-acceptable intimate mixtures of active ingredients and excipients which meet economic performance levels are prepared without use of harmful solvents by solubilizing and mixing the components in liquid carbon dioxide maintained under pressure and then slowly reducing the pressure to convert the carbon dioxide to the gaseous phase and venting the gaseous carbon dioxide.

Method of preparing mixtures of active ingredients and excipients using liquid carbon dioxide

Compounds of the formula I and II ##STR1## wherein R 1 , R 2 and R 3 independently of one another are each hydrogen, C 1 -C 4 -alkyl, methoxy, halogen, trifluoromethyl or nitro, R 4 is hydrogen or methyl, R 5 is C 1 -C 3 -alkyl, R 6 is C 1 -C 6 -alkyl, C 2 -C 6 -aklenyl, C 3 -C 5 -alkynyl, C 3 -C 6 -cycloalkyl, C 2 -C 4 -(alkoxyalkyl) or C 2 -C 4 -(alkylthioalkyl), and R 7 is C 1 -C 12 -alkyl, C 3 -C 5 -alkenyl or C 3 -C 8 -cycloalkyl, and the acid addition salts of compounds of the formulae I, are novel. The compounds of the formula II can be used as starting materials for producing compounds of the formula I. The mentioned compounds of the formulae I and II have a pesticidal action, especially an acaricidal and insecticidal action, and are particularly effective against plant pest

Thiourea derivatives having pesticidal activity

ARYLPROPARGYL-ETHERS AND ARYLPROPARGYL-THIOETHERS OF THE FORMULA ARY-X-CH2-C$C-R1 IN WHICH X REPRESENTS AN OXYGEN OR A SULPHUR ATOM, AND R1 REPRESENTS A HYDROGEN ATOM, A HALOGEN ATOM, AN ALKYL GROUP HAVING FROM 1 TO 7 CARBON ATOMS OR AN UNSUBSTITUTED OR SUBSTITUTED AROMATIC HYDROCARBON RADICAL, AS SYNERGISTIC AGENTS TO BIOCIDALLY ACTIVE COMPOUNDS OTHER THAN CARBAMIC ACID DERIVATIVES.

Synergistically activated biocidal compositions

Aryl thiourea fruit abcission method

Compounds of the formula ##SPC1## Wherein R1 is an alkoxyalkyl or alkylthio alkyl radical and R2 is hydrogen, a lower alkyl or lower alkenyl radical, Herbicidal compositions containing them and their use as selective herbicides are described.

Phenyl ureas, their use as selective herbicides

Substituted carbanilic acid propargyl esters of the formula IN WHICH R1, R2 and R4, which may be the same or different, each represents a hydrogen atom or a halogen atom or an alkyl, alkoxy or halogenalkyl radical each having from one to four carbon atoms or a -NO2 or -SCN group, and R4 and R5, which may be the same or different, each represents a hydrogen atom or an alkyl group having from one to four carbon atoms, used as synergistic agents for insecticidally and/or a acaricidally active substances.

Pissiotas G

Papers

Synergistically activated biocidal compositions

Aryl thiourea fruit abcission method

Phenyl ureas, their use as selective herbicides

Insecticidal and acaricidal substituted carbanilic acid esters

Phenylharnstoffe,ihre Herstellung und Verwendung als Herbizide