R. Gavars

TL;DR: In this paper, rotating ring-disk electrode (RRDE) voltammetry has been used for studying the electrochemical oxidation processes of N-substituted 2,6-dimethyl-3,5-di(ethoxycarbonyl)-1,4- and 1,2-dihydropyridines in acetonitrile.

TL;DR: In this article, the primary and secondary chemical reactions occurring during electrochemical reduction of the title compounds are discussed, as well as the intermediate 1,6-Dimethyl-3,5-dicyano-4-(para-, meta-nitrophenyl)-2-pyridonemethide (VIa, b) was identified as intermediate.

TL;DR: In this article, the ERS spectra of anion radicals for 29 derivatives of 5-nitrofuran, electrochemically generated in situ, have been obtained and studied using spectral HFS constants and quantum chemical model parameters.

TL;DR: In this article, the effect of substituents in position 2 of 5-nitrofurans on half-wave potentials of the first and second stage of electroreduction was quantitatively evaluated for these compounds using life (linearity of free energy) relationships.

TL;DR: In this paper, a detailed study of the electroreduction of 50 5-nitrofuran derivatives in various media has been carried out, using classical and oscillographic polarography, Kemula cyclic chronovoltammetry, the Kalousek commutative technique, U.S. and E.V.R. spectrometry, and quantum chemical calculations.