Starch, cellulose, pectin, gum, alginate, chitin and chitosan derived (nano)materials for sustainable water treatment: A review

Synthesis and antioxidant properties of gum arabic-stabilized selenium nanoparticles.

Recent progresses in the application of cellulose, starch, alginate, gum, pectin, chitin and chitosan based (nano)catalysts in sustainable and selective oxidation reactions: A review

Tree gum-based renewable materials: Sustainable applications in nanotechnology, biomedical and environmental fields.

The purpose of this study was to design and synthesize Palladium nanoparticles (PdNPs) using an environmentally friendly approach and evaluate the in vitro efficacy of PdNPs in human ovarian cancer A2780 cells. Ultraviolet-Visible (UV-Vis) spectroscopy was used to monitor the conversion of Pd(II) ions to Pd(0)NPs. X-ray diffraction (XRD) revealed the crystallinity of the as-synthesized PdNPs and Fourier transform infrared spectroscopy (FTIR) further confirmed the role of the leaf extract of Evolvulus alsinoides as a reducing and stabilizing agent for the synthesis of PdNPs. Dynamic light scattering (DLS) and transmission electron microscopy (TEM) showed that the average size of the NPs was 5 nm. After a 24-h exposure to PdNPs, cell viability and light microscopy assays revealed the dose-dependent toxicity of the PdNPs. Furthermore, the dose-dependent cytotoxicity of the PdNPs was confirmed by lactate dehydrogenase (LDH), increased reactive oxygen species (ROS) generation, activation of PdNPs-induced autophagy, impairment of mitochondrial membrane potential (MMP), enhanced caspase-3 activity, and detection of TUNEL-positive cells. Our study demonstrates a single, simple, dependable and green approach for the synthesis of PdNPs using leaf extracts of Evolvulus alsinoides. Furthermore, the in vitro efficacy of PdNPs in human ovarian cancer cells suggests that it could be an effective therapeutic agent for cancer therapy.

Green Chemistry Approach for Synthesis of Effective Anticancer Palladium Nanoparticles

This article presents the findings of a facile and effective nanoparticle synthesis approach based on aqueous solutions of gum acacia (GA), also known as gum arabic without the addition of any toxic reagents either for the reduction or capping for the effective stabilization of palladium (Pd) nanoparticles with a narrow size distribution (with a H 2 PdCl 4 /GA ratio of 1:29.411, the solution the average diameter was 9.1 nm, and the standard deviation was ±0.3 nm). In this approach, the particle size was controlled by the manipulation of the temperature, time, and concentration of GA. The synthesized Pd nanoparticles were well characterized by ultraviolet-visible spectroscopy, Fourier transform infrared spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, dynamic light scattering, and thermogravimetric analysis. This route was very simple and reproducible, and further study on the application of these nanoparticles for various organic transformations is underway.

R. Haritha

Papers

Gum acacia as a facile reducing, stabilizing, and templating agent for palladium nanoparticles