Trace and minor elements in sphalerite: A LA-ICPMS study

Metalliferous coals: A review of the main genetic and geochemical types

The “chessboard” classification scheme of mineral deposits: Mineralogy and geology from aluminum to zirconium

Cu2Zn(Sn1−xGex)S4 nanocrystals have been synthesized via batch reaction in oleylamine with no additional surfactants present. The nanocrystals are knife-coated on molybdenum substrates and then selenized to form a dense layer of Cu2Zn(Sn1−xGex)(S,Se)4, which is then used as the photoabsorbing layer in a thin film solar cell. The band gaps of the nanocrystals and the resulting solar cells are demonstrated to be controlled by adjusting the Ge/(Ge+Sn) ratio of the nanocrystal synthesis precursors. Solar cells fabricated from Cu2ZnGeS4 nanocrystal films yielded a power conversion efficiency of 0.51%. However, Cu2Zn(SnxGe1−x)S4 nanocrystals with a Ge/(Ge+Sn) ratio 0.7 yielded devices with an efficiency of 6.8% when synthesized to be Cu-poor and Zn-rich. This result opens the possibility of forming Ge gradients to direct minority carriers away from high recombination interfaces and significantly improve the device efficiency of CZTSSe-based solar cells.

R. Höll

Papers

Metallogenesis of germanium—A review