The E factor 25 years on: the rise of green chemistry and sustainability

Bioethanol is one of the most promising and eco-friendly alternatives to fossil fuels, which is produced from renewable sources. Although almost all the current fuel ethanol is generated from edible sources (sugars and starch), lignocellulosic biomass (LCB) has drawn much attention in recent times. However, the conversion efficiency as well as ethanol yield of the biomass differs greatly with respect to the source and nature of LCB, primarily due to the variation in lignocellulosic content. Two major polysaccharides in LCB, namely, cellulose and hemicellulose firmly link to lignin and form a complex lignocellulosic network, which is highly robust and recalcitrant to depolymerization. For this reason, generation of ethanol from LCB requires a complicated conversion process that has made it commercially non-competitive. As attempts to exploit LCBs into commercial ethanol production, recent research efforts have been devoted to the techno-economic improvements of the overall conversion process, in addition to screen out promising feedstocks. This review paper presents an overview on the diversity of biomass, technological approaches and microbial contribution to the conversion of LCB into ethanol.

Fuel ethanol production from lignocellulosic biomass: an overview on feedstocks and technological approaches.

Agricultural residues are rich in bioactive compounds. These residues can be used as an alternate source for the production of different products like biogas, biofuel, mushroom, and tempeh as the raw material in various researches and industries. The use of agro-industrial wastes as raw materials can help to reduce the production cost and also reduce the pollution load from the environment. Agro-industrial wastes are used for manufacturing of biofuels, enzymes, vitamins, antioxidants, animal feed, antibiotics, and other chemicals through solid state fermentation (SSF). A variety of microorganisms are used for the production of these valuable products through SSF processes. Therefore, SSF and their effect on the formation of value-added products are reviewed and discussed.

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Agro-industrial wastes and their utilization using solid state fermentation: a review

Bioethanol is an attractive biofuel having potential for energy security and environmental safety over fossil fuels. To date, numerous biomass resources have been investigated for bioethanol production, which can broadly be classified into sugars, starch and lignocellulosic biomass. However, conversion of biomass into ethanol varies considerably depending on the nature of feedstock, primarily due to the variation in biochemical composition, and so, only a few feedstocks have been exploited commercially. In recent years, the conversion process of biomass has been improved significantly, even though most of these achievements are yet to be implemented in commercial facility. All the major steps in a typical conversion process, particularly fermentation of sugars that is the common step for all biomass, are greatly influenced by microorganisms. A traditional yeast, Saccharomyces cerevisiae, and a bacterial species, Zymomonas mobilis, are widely used in the ethanol fermentation technology. Many factors affect ethanol production process, and the final yield is directly associated with the optimum conditions of these attributes. This review paper presents an overview on the first and second generation bioethanol production with a particular attention to the potential of various biomass sources, technological approaches, role of microorganisms and factors affecting ethanol production process.

Bioethanol production from renewable sources: Current perspectives and technological progress

It is a popular fact that the world's dependency on fossil fuel has caused unfavourable effects, including lessening crude oil reserve, decreasing air quality, rising global temperature, unpredictable weather change, and so on. As the effort to promote sustainability and independency from fossil fuel, bioethanol is now favoured as the blend or fossil petrol substitute. However, the feedstock functionality of first generation bioethanol production is restricted due to its edibleness since it would clash the feeding purpose. Second generation bioethanol production fulfils the impractical gap of first generation since it employs non-edible feedstock sourced from agriculture and forestry wastes. Lignocellulosic and starchy materials in them are convertible to fermentable sugars that are able to be further processed, resulting anhydrous bioethanol as the end product. This paper critically reviews the existing variance of second generation bioethanol production methodologies, namely pre-treatment, hydrolysis, fermentation and distillation, as well as the worth of second generation production for future reference. The discussions in this paper are also fit as the fundamental for feasible planning of second generation bioethanol production plant.

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Second generation bioethanol production: A critical review

Production of liquid biofuels, such as bioethanol, has been advocated as a sustainable option to tackle the problems associated with rising crude oil prices, global warming and diminishing petroleum reserves. Second-generation bioethanol is produced from lignocellulosic feedstock by its saccharification, followed by microbial fermentation and product recovery. Agricultural residues generated as wastes during or after processing of agricultural crops are one of such renewable and lignocellulose-rich biomass resources available in huge amounts for bioethanol production. These agricultural residues are converted to bioethanol in several steps which are described here. This review enlightens various steps involved in production of the second-generation bioethanol. Mechanisms and recent advances in pretreatment, cellulases production and second-generation ethanol production processes are described here.

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Reetu Saini

Papers

Lignocellulosic agriculture wastes as biomass feedstocks for second-generation bioethanol production: concepts and recent developments

Bioethanol production from wheat straw via enzymatic route employing Penicillium janthinellum cellulases.

Enhanced cellulase production by Penicillium oxalicum for bio-ethanol application.

An integrative process for bio-ethanol production employing SSF produced cellulase without extraction

Algae as an emerging source of bioactive pigments.