Showing papers by "Richard D. Adams published in 2017"
TL;DR: In this paper, the reaction of Re2(CO)8[μ-η2-C(H) = C(H)-Bun](μ-H), 1 with N,N-dimethylformamide (DMF) at 70c for 6h has yielded three new compounds.
9 citations
01 Jan 2017
TL;DR: The PASTA project as mentioned in this paper aims to connect transport and health by promoting active mobility in cities (ie walking and cycling) including in combination with public transport use, as an innovative way of integrating physical activity into our everyday lives.
Abstract: The EU-funded project PASTA - Physical Activity Through Sustainable Transport Approaches - aimed to connect transport and health by promoting active mobility in cities (ie walking and cycling) including in combination with public transport use) as an innovative way of integrating physical
activity into our everyday lives
3 citations
TL;DR: The reaction of Ru5(μ5-C)(CO)15, 1 with MeAu(PPh3) yielded two major products as mentioned in this paper, and one minor product, which was obtained independently in 57% yield by the addition of CO to 5.
2 citations
TL;DR: Two isomers of Ru5(C)(CO)14(O2CC6H5)(μ-H) were obtained from the reaction of Ru1C(CO)15 with benzoic acid (PhCO2H).
Abstract: Two isomers of Ru5(C)(CO)14(O2CC6H5)(μ-H): Ru5(C)(CO)14(η2-O2CC6H5)(μ-H), 2 and Ru5(C)(CO)14(μ-O2CC6H5)(μ-H), 3 were obtained from the reaction of Ru5(C)(CO)15 with benzoic acid (PhCO2H). Both compounds were characterized structurally by X-ray diffraction analysis. Compound 2 contains an opened pentaruthenium cluster with a chelating benzoate ligand on the ruthenium atom that was opened. Compound 3 contains an opened pentaruthenium cluster with a benzoate ligand on that bridges a pair of ruthenium atoms which are not mutually bonded. Compound 2 can be converted partially to 3 and 3 partially back to 2 and they form a 1.54/1.0 ratio (3/2) at equilibrium in solution at 95 °C.
1 citations