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Showing papers by "Richard J. Saykally published in 1979"


Journal ArticleDOI
TL;DR: A molecular ion (H${\mathrm{Br}}^{+}$) has been observed for the first time by laser magnetic resonance spectroscopy as discussed by the authors, and pure rotational transitions have been detected with five different far-infrared laser lines.
Abstract: A molecular ion (H${\mathrm{Br}}^{+}$) has been observed for the first time by laser magnetic resonance spectroscopy. Pure rotational transitions have been detected with five different far-infrared laser lines. Assignment of the hyperfine patterns has produced values for the magnetic hyperfine constants.

48 citations


Journal ArticleDOI
TL;DR: In this paper, the J=2→1 fine-structure splitting in the ground state of atomic oxygen was measured by laser magnetic resonance employing an intracavity dc glow discharge to generate the atom.
Abstract: The J=2→1 fine‐structure splitting in the ground state of atomic oxygen has been measured by laser magnetic resonance employing an intracavity dc glow discharge to generate the atom. The splitting, observed with the 63.1 μm laser line of 13CH3OH pumped by a CO2 laser, is 158.30298 (7) cm−1.

32 citations