R
Robert Lesclaux
Researcher at University of Bordeaux
Publications - 111
Citations - 3507
Robert Lesclaux is an academic researcher from University of Bordeaux. The author has contributed to research in topics: Reaction rate constant & Flash photolysis. The author has an hindex of 36, co-authored 111 publications receiving 3358 citations.
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Journal ArticleDOI
Pressure and temperature dependence of amino radical recombination rate constant
Journal ArticleDOI
The phenoxy radical: UV spectrum and kinetics of gas-phase reactions with itself and with oxygen
Florence Berho,Robert Lesclaux +1 more
TL;DR: The kinetics of the gas-phase reactions of the phenoxy radical with itself and with oxygen were investigated using flas photolysis coupled to UV absorption spectrometry at 760 Torr, using N 2 as the buffer gas as discussed by the authors.
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Kinetics and thermochemistry of the equilibrium trichloromethyl radical + oxygen .dblarw. peroxotrichloromethane
J. J. Russell,J. A. Seetula,D. Gutman,F. Danis,Françoise Caralp,P. D. Lightfoot,Robert Lesclaux,Carl F. Melius,S. M. Senkan +8 more
TL;DR: In this article, the CH{sub 3}-O{sub 2} bond was shown to weaken with chlorine substitution on the CH-sub 3 group, from 32.4 kcal to 19.9 kcal.
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Study of the kinetics and equilibrium of the benzyl‐radical association reaction with molecular oxygen
TL;DR: The forward rate constant, k1, and the equilibrium constant, Kp, for the association reaction of the benzyl radical with oxygen have been determined in this paper, where the reaction is independent of pressure and is almost independent of temperature.
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UV absorption spectra of HO2 and CH3O2 radicals and the kinetics of their mutual reactions at 298 K
TL;DR: In this article, a flash photolysis study of the UV, spectra of HO2 and CH3O2 radicals, obtained by using a calibration technique based on the reaction Cl+NO→NOCl.