Rodrigo París

TL;DR: In this article, a detailed investigation of the polymerization of allyl methacrylate, a typical unsymmetrical divinyl compound containing two types of vinyl groups, methaceloyl and allyl, with quite different reactivities, was performed with atom transfer radical polymerization (ATRP).

TL;DR: In this article, the controlled radical polymerization of allyl methacrylate by atom transfer radical polymers was carried out in solution at 70 °C, with ethyl 2-bromoisobutyrate as the initiator and copper halide (CuX, where X is Cl or Br) with N,N,N',N', N, N-pentamethyldiethylenetriamine as the catalyst system, and the prepared polymers were characterized by size exclusion chromatography, Fourier transform infrared, and one-and two-

TL;DR: In this article, the glass transition temperatures of spontaneous gradient copolymers of P(AMA-co-BA) were measured using differential scanning calorimetry, where the expected increase in Tg with the augment of the monomer conversion is compensated by the enrichment of BA as the polymerization reaction progresses.

TL;DR: In this article, spontaneous gradient copolymers of allyl methacrylate and butyl acrylate were synthesized via atom transfer radical polymerization, and different aspects of the reaction copolymerizations, such as the kinetic behavior, crosslinking density, and gel fraction, were studied.

TL;DR: In this paper, a bi-functional statistical copolymers based on allyl methacrylate (AMA) and GMA were synthesized via atom transfer radical polymerization (ATRP) in a diphenyl ether solution at low temperature, 50°C.