the NSFC (Nos. 21272100);Program for Changjiang Scholars and Innovative Research Team in University (PCSIRT: IRT1138);Research Fund for the Doctoral Program of Higher Education of China (Nos. 20100211120014)

Direct annulations toward phosphorylated oxindoles: silver-catalyzed carbon-phosphorus functionalization of alkenes.

6-Phosphorylated Phenanthridines from 2-Isocyanobiphenyls via Radical C–P and C–C Bond Formation

A versatile protocol for preparation of various di(phenyl)phosphoryl oxides is developed by copper-catalyzed decarboxylative coupling of alkenyl, alkynyl carboxylic acids, and N-benzylproline, respectively, with R2P(O)H.

Copper‐Catalyzed C–P Coupling through Decarboxylation

A new method for the P-arylation of aryldiazonium salts with H-phosphonates via dual gold and photoredox catalysis is described. The reaction proceeds smoothly at room temperature in the absence of base and/or additives, and offers an efficient approach to arylphosphonates. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes coupling with the H-phosphonate nucleophile.

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Sarah Van der Jeught

Papers

Direct phosphonylation of aromatic azaheterocycles.

Ring-closing metathesis and ring-closing metathesis–isomerisation approach to 1-phosphonylated 2-benzazocines

Kharasch-Type Cyclizations of 2-Substituted Indole Derivatives Surprisingly Lead to Spiroindoles

A Straightforward Entry to 7-Azabicyclo[2.2.1]heptane-1-carbonitriles in the Synthesis of Novel Epibatidine Analogues

Synthesis of Phosphonobenzocarbacephems by Intramolecular Radical Cyclization of Haloaryl-Substituted β-Lactams