https://publikationen.bibliothek.kit.edu/1000050288/18451059

Renewable Power-to-Gas: A technological and economic review

Power-to-Methane is a concept that converts electrical into chemical energy using CO2 and H2O. The concept brings the possibility of connecting the power grid to different sectors, where CH4 is needed such as mobility and industry. In this review, a comprehensive overview of the state-of-the-art of Power-to-Methane is presented. The Power-to-Methane process chain is described in detail. Fundamentals of water electrolysis are highlighted and cell technologies are discussed and assessed. CO2 sources are pointed out, CO2 separation technologies are depicted and compared, and some separation projects worldwide are listed. Thermodynamics of methanation process is analyzed; catalysts and reactors used are descripted and evaluated. Finally, Power-to-Methane plants in operation and construction are addressed.

Power-to-Methane: A state-of-the-art review

Biogas is acknowledged as one of the foremost bioenergy to address the current environmental and energy challenges being faced by the world. Commonly, biogas is used for applications like cooking, lighting, heat and power production. To widen the scope of biogas application, like transportation, natural gas grid injection and substrate for the production of chemicals and fuel cells, mainly CO2, H2S and other impurities need to be removed by various upgrading technologies. It is an important process to produce biomethane with above 90% methane. There are various physico-chemical (adsorption, absorption, cryogenic and membrane separations) and biological (in situ and ex situ) processes for biogas upgradation, and each process is site and case specific. The aim of the present paper is to thoroughly evaluate the existing and emerging biogas upgrading technologies. Analysis of each technology with respect to basis of operations, energy requirement, methane purity and recovery and cost economics has been carried out. A thorough analysis has been done on the major hurdles and the research gaps in this sector. For a wider and successful implementation of the biogas upgradation technology, the trends in research and development (R&D) such as development of efficient biogas upgrading technologies, adsorbents, reduction in cost and methane loss have been thoroughly evaluated.

Evaluation of biogas upgrading technologies and future perspectives: a review

Hydrogen-oxidizing bacterium, Alcaligenes eutrophus autotrophically produces biodegradable plastic material, poly(D-3-hydroxybutyrate), P(3HB), from carbon dioxide, hydrogen, and oxygen. In autotrophic cultivation of the microorganism, it is essential to eliminate possible occurrence of gas explosions from the fermentation process. We developed a bench-plant scale, recycled-gas, closed-circuit culture system equipped with several safety features to perform autotrophic cultivation of A. eutrophus by maintaining the oxygen concentration in the substrate gas phase below the lower limit for a gas explosion (6.9%). The culture vessel utilized a baskettype agitator, resulting in a K(L) a value of 2970 h(-1). Oxygen gas was also directly fed to the fermentor separately from the other gases. As a result, 91.3 g . dm(-3) of the cells and 61.9 g . dm(-3) of P(3HB) were obtained after 40 h of cultivation under this oxygen-limited condition. The results compared favorably with those reported for mass production of P(3HB) by heterotrophic fermentation. (c) 1995 John Wiley & Sons, Inc.

Production of poly(D‐3‐hydroxybutyrate) from CO2, H2, and O2 by high cell density autotrophic cultivation of Alcaligenes eutrophus

This short review covers the biotechnological aspects of the production of poly-D-3-hydroxybutyric acid, P(3HB), from H2, O2 and CO2 by autotrophic culture of the hydrogen-oxidizing bacterium, Ralstonia eutropha. Considering the efficiency of utilization of a gas mixture as substrate, a practical fermentation process using R. eutropha for the mass production of P(3HB) from CO2 should be designed on the basis of a recycled-gas, closed-circuit culture system. Also, maintaining the O2 concentration in a gas phase lower than 6.9% (v/v) is essential to prevent the gas mixture from exploding. Our study, using an explosion-proof fermentation bench plant and a two-stage culture system with a newly designed air-lift fermenter, demonstrated that very high P(3HB) yield and productivity could be obtained while the O2 concentration was maintained below 6.9%. However, a study on the continuous production of P(3HB) from CO2 by chemostat culture of R. eutropha revealed that the productivity and content of P(3HB) in the cells was considerably lower than by fed-batch culture. It is deduced that the use of the hydrogen-oxidizing bacterium, Alcaligenes latus, which accumulates P(3HB) even in the exponential growth phase, will be useful for the effective production of P(3HB) from CO2.

Shinko Kitaura

Papers

Cultivation of thermophilic methanogen KN-15 on H2-CO2 under pressurized conditions

Growth of thermophilic methanogen KN-15 on H2-CO2 under batch and continuous conditions

Isolation and characterization of a fast-growing, thermophilic, hydrogenotrophic methanogen