Response of dissolved organic carbon in rainwater during extreme rainfall period in megacity: Status, potential source, and deposition flux

Influence of using different chemical mechanisms on simulations of ozone and its precursors in the troposphere of Shanghai, China

Wet deposition is influencing air quality because air pollutants are washed away from the surrounding air. Consequently, particulate matter and associated compounds are transported in the rainwater and enter into soil, surface waters, and groundwater. Nonpoint sources of heavy metals from stormwater runoff have increased in urban areas due to industrialization and the increasing impervious surfaces. In this work, we present an assessment of the rainwater composition regarding the nutrients and other physicochemical characteristics measured in three locations selected in Targoviste city, Romania, a city that had a specialized steel factory and important metallurgical facilities. The rainwater was collected using three PALMEX rain samplers and then was transferred to high-density polyethylene bottles and analyzed using ICP-MS. PM2.5 concentrations were also monitored continuously using optical monitors calibrated using a gravimetric sampler. A detailed analysis of the heavy metals content in rainwater and PM was presented for the pollution episodes occurring in October and November 2019. Backward trajectories were computed using the HYSPLIT model for these periods. The results showed that the PM2.5 ranged from 11.1 to 24.1 μg/m3 in 2019, while the heavy metals in collected rainwater were (µg L−1): 0.25 (Cd) − CV = 26.5%, 0.10 (Co) − CV = 58.1%, 1.77 (Cr) − CV = 24.3%, 377.37 (Ni) − CV = 27.9%, 0.67 (Pb) − CV = 74.3%, and 846.5 (Zn) − CV = 20.6%. Overall, Ni, Pb, Cr, and V had significant correlations between the concentrations from rainwater and PM. Negative associations were found between precipitation events and heavy metals both from rainwater and PM, but only a few showed statistical significance. However, this could explain the “washing” effect of the rain on the heavy metals from PM2.5. The potential sources of nitrogen in the rainwater collected in Targoviste could be from burning fossil fuels and the soils, including both biological processes and fertilization resulting from the intensive agriculture in the piedmont plain in which the city is located. Based on the results, rainwater monitoring can constitute a reliable method for air quality characterization. Additional research is required to better understand seasonality and sources of heterogeneity regarding the associations between PM and rainwater composition.

Monitoring Rainwater Properties and Outdoor Particulate Matter in a Former Steel Manufacturing City in Romania

“Outdoor Air Pollution and Human Health” addresses one of the most critical areas of concern in society [...]

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Outdoor Air Pollution and Human Health

For the first time, the change in the physicochemical properties, ions composition, concentrations, and ratio of soluble and insoluble potentially toxic elements (PTEs), as well as sources contribution to the content of PTEs using principal component analysis with multiple linear regression (PCA-MLR) were determined in the Moscow precipitation before, during and after the lockdown (January–July 2020). The impact of the lockdown on the precipitation composition was ambivalent. The decrease in the precipitation pollution with PTEs (by 10–99% for soluble PTEs and 9–61% for insoluble ones) was caused by the purification of the atmosphere from aerosols during their long-term washing out by precipitation and a decrease in anthropogenic emissions. Air advection to Moscow from the suburbs, where wood, coal, household and agricultural wastes were burned, on the contrary, contributed to the growth of precipitation pollution with insoluble P, Pb, Cd, soluble P, Ag, Pb, Sb, As, Cd, as well as [Cl−] and [K+]. After the lockdown, the restoration of the level of precipitation pollution by PTEs occurred gradually due to the time lag between the increase in atmospheric pollution and the washing out of aerosols by precipitation, as well as dilution by exceptional rainfall amount. Faster restoration rates of insoluble PTEs compared to soluble ones are associated with the rapid increase in the activity of the urban source (road and construction dust, industrial and traffic emissions). The lifting lockdown restrictions reduced the contribution of industrial sources to the content of soluble PTEs forms (from 38–66% to 6%) due to an increase in the contribution of road dust and non-exhaust emissions, soil particles resuspension, waste and fuel combustion, and vehicle emissions. A decrease in the contribution of vehicle emissions, road dust resuspension, and construction dust to the content of insoluble PTEs from winter to summer due to the lockdown influence and a large amount of precipitation in late spring and early summer was confirmed. The results highlighted the need for further studies of the chemical composition and properties of precipitation in the city in similar periods for the correct separation of the influence of social, economic, emission, meteorological, and physicochemical factors on the content and the ratio of PTEs forms. 

Major ions and potentially toxic elements in atmospheric precipitation during the COVID-19 lockdown in Moscow megacity

Air pollutants have been investigated in many studies, but the variations of atmospheric pollutants and their relationship with rainwater chemistry are not well studied. In the present study, the criteria atmospheric pollutants in nine monitoring stations and rainwater chemistry were analyzed in karst Guiyang city, since the time when the Chinese Ambient Air Quality Standards (CAAQS, third revision) were published. Based on the three-year daily concentration dataset of SO2, NO2, CO, PM10 and PM2.5, although most of air pollutant concentrations were within the limit of CAAQS III-Grade II standard, the significant spatial variations and relatively heavy pollution were found in downtown Guiyang. Temporally, the average concentrations of almost all air pollutants (except for CO) decreased during three years at all stations. Ratios of PM2.5/PM10 in non- and episode days reflected the different contributions of fine and coarse particles on particulate matter in Guiyang, which was influenced by the potential meteorological factors and source variations. According to the individual air quality index (IAQI), the seasonal variations of air quality level were observed, that is, IAQI values of air pollutants were higher in winter (worst air quality) and lower in summer (best air quality) due to seasonal variations in emission sources. The unique IAQI variations were found during the Chinese Spring Festival. Air pollutant concentrations are also influenced by meteorological parameters, in particular, the rainfall amount. The air pollutants are well scoured by the rainfall process and can significantly affect rainwater chemistry, such as SO42−, NO3−, Mg2+, and Ca2+, which further alters the acidification/alkalization trend of rainwater. The equivalent ratios of rainwater SO42−/NO3− and Mg2+/Ca2+ indicated the significant contribution of fixed emission sources (e.g., coal combustion) and carbonate weathering-influenced particulate matter on rainwater chemistry. These findings provide scientific support for air pollution management and rainwater chemistry-related environmental issues.

https://www.mdpi.com/2073-4433/12/8/1073/pdf

Shitong Zhang

Papers

Three-Year Variations in Criteria Atmospheric Pollutants and Their Relationship with Rainwater Chemistry in Karst Urban Region, Southwest China