Synthesis and characterisation of copper complexes with N-ferrocenoyl-N′-aryl(alkyl)thioureas

Synthesis and Structural Characterization of a Bitopic Ferrocenyl-Linked Bis(pyrazolyl)methane Ligand and Its Silver(I) Coordination Polymers

New six coordinated tris-chelate cobalt(III) complexes of the type [Co(L)3] (1–4) {where HL = N-[di(alkyl/aryl)carbamothioyl]benzamide derivatives}were prepared from the reaction between CoCl2·6H2O and N-[di(alkyl/aryl)carbamothioyl]benzamide in ethanol and characterized by elemental analysis and spectral data (UV/Vis, IR, 1H & 13C NMR). The molecular structure of a representative complex [Co(L1)3] (1) [where HL1 = N-(diisopropylcarbamothioyl)benzamide], was determined by single crystal X-ray diffraction method and reveals a distorted octahedral geometry and a facial configuration of S atoms around the Co(III) center. These complexes act as efficient catalysts for the oxidation of alcohols to their corresponding aldehydes or ketones in presence of tert-butyl hydroperoxide (TBHP) at 80 °C.

Tris-chelate complexes of cobalt(III) with N-[di(alkyl/aryl)carbamothioyl] benzamide derivatives: Synthesis, crystallography and catalytic activity in TBHP oxidation of alcohols

Synthesis and characterisation a series of N-(3,4-dichlorophenyl)-N′-(2,3 and 4-methylbenzoyl)thiourea derivatives

An efficient and recyclable thiourea-supported copper(I) chloride catalyst for azide–alkyne cycloaddition reactions

Studies on intramolecular hydrogen bonding of 1,1′-bis[N-formyl-N′-p-chlorophenylthiourea]ferrocene

Coordination compounds derived from 1,1′-bis(N-formyl-N′-substituted thiourea)ferrocene derivatives have been prepared Elemental analyses indicate the presence of a 1:1 metal-to-ligand ratio Ir and 1H-nmr spectra show that the intramolecular hydrogen bonds in the corresponding ligands remain intact upon coordination The single crystal structure of one such compound, a coordination polymer, was determined CuII was reduced to CuI during the coordination process

Coordination compounds derived from 1,1′-bis(N-formyl-N′-substituted thiourea)ferrocene derivatives and copper chloride; crystal structure of the copper chloride 1,1′-bis(N-formyl-N′-isopropylthiourea)ferrocene coordination polymer

Synthesis and intramolecular hydrogen bonding studies of 1-[ N -formyl- N ′, N ′-disubstituted thiourea]-1′-[ N ′ , N ′-disubstituted amide]ferrocene derivatives

Synthesis and properties of some 1,1′-bis[ N -formyl- N ′-substituted thiourea]ferrocene derivatives: crystal structure of 1,1′-bis[ N -formyl- N ′- p -chlorophenylthiourea]ferrocene

Su-ming Ye

Papers

Studies on intramolecular hydrogen bonding of 1,1′-bis[N-formyl-N′-p-chlorophenylthiourea]ferrocene

Coordination compounds derived from 1,1′-bis(N-formyl-N′-substituted thiourea)ferrocene derivatives and copper chloride; crystal structure of the copper chloride 1,1′-bis(N-formyl-N′-isopropylthiourea)ferrocene coordination polymer

Synthesis and intramolecular hydrogen bonding studies of 1-[ N -formyl- N ′, N ′-disubstituted thiourea]-1′-[ N ′ , N ′-disubstituted amide]ferrocene derivatives

Synthesis and properties of some 1,1′-bis[ N -formyl- N ′-substituted thiourea]ferrocene derivatives: crystal structure of 1,1′-bis[ N -formyl- N ′- p -chlorophenylthiourea]ferrocene