This critical review shows the basis of photocatalytic water splitting and experimental points, and surveys heterogeneous photocatalyst materials for water splitting into H2 and O2, and H2 or O2 evolution from an aqueous solution containing a sacrificial reagent Many oxides consisting of metal cations with d0 and d10 configurations, metal (oxy)sulfide and metal (oxy)nitride photocatalysts have been reported, especially during the latest decade The fruitful photocatalyst library gives important information on factors affecting photocatalytic performances and design of new materials Photocatalytic water splitting and H2 evolution using abundant compounds as electron donors are expected to contribute to construction of a clean and simple system for solar hydrogen production, and a solution of global energy and environmental issues in the future (361 references)

Heterogeneous photocatalyst materials for water splitting

2.3. Evaluation of Photocatalytic Water Splitting 6507 2.3.1. Photocatalytic Activity 6507 2.3.2. Photocatalytic Stability 6507 3. UV-Active Photocatalysts for Water Splitting 6507 3.1. d0 Metal Oxide Photocatalyts 6507 3.1.1. Ti-, Zr-Based Oxides 6507 3.1.2. Nb-, Ta-Based Oxides 6514 3.1.3. W-, Mo-Based Oxides 6517 3.1.4. Other d0 Metal Oxides 6518 3.2. d10 Metal Oxide Photocatalyts 6518 3.3. f0 Metal Oxide Photocatalysts 6518 3.4. Nonoxide Photocatalysts 6518 4. Approaches to Modifying the Electronic Band Structure for Visible-Light Harvesting 6519

Semiconductor-based Photocatalytic Hydrogen Generation

UV-Visible ار راد ن .د TiO2 ( تیفرظ راون مان هب نورتکلا یاراد یژرنا زارت لماش VB و ) رگید زارت ی یژرنا اب ( ییاناسر راون مان هب نورتکلا زا یلاخ و رتلااب VB یم ) .دشاب ت ود نیا نیب یژرنا توافت یژرنا فاکش زار ، پگ دناب هدیمان یم .دوش هک ینامز زا نورتکلا لاقتنا VB هب VB یم ماجنا دریگ ، TiO2 اب ودح یژرنا بذج د ev 2 / 3 ، نورتکلا تفج کی دیلوت یم هرفح .دیامن و نورتکلا هرفح ی نا اب هدش دیلوت یم کرتشم حطس هب لاقت ثعاب دناوت شنکاو ماجنا اه یی ددرگ . TiO2 دربراک ،دراد یدایز یاه هلمج زا یم ناوت اوه یگدولآ هیفصت یارب (CO2) و بآ و ... نآ زا هدافتسا درک .

Advanced Nanoarchitectures for Solar Photocatalytic Applications

Photocatalytic and photoelectrochemical (PEC) water splitting using semiconductor materials has attracted considerable interest due to its potential to cleanly produce H 2 from water by utilizing abundant solar light. Since Fujishima and Honda used a TiO 2 photoanode in 1972 to split water, researchers have been attempting to develop water-splitting systems that can efficiently use visible light (which accounts for almost half of the solar spectrum on the Earth's surface) in order to realize efficient conversion of solar light. In this report, we review recent progress in this field by focusing on strategies that utilize visible light. Such strategies include two-step photoexcitation systems that were inspired by photosynthesis in nature, band engineering for producing novel photocatalysts that have both a high visible light absorption and suitable energy levels for water splitting, the development of new cocatalysts for efficient H 2 or O 2 production, fabrication of efficient photoelectrodes based on visible-light-responsive semiconductors, and the construction of tandem-type PEC water-splitting systems.

Recent progress on photocatalytic and photoelectrochemical water splitting under visible light irradiation

Overall water splitting to produce H 2 and O 2 over a semiconductor photocatalyst using solar energy is a promising process for the large-scale production of clean, recyclable H 2 . Numerous attempts have been made to develop photocatalysts that function under visible-light irradiation to efficiently utilize solar energy. In general, overall water splitting over a photocatalyst particle can be achieved by modifying the photocatalyst with a suitable cocatalyst to provide an active redox site. Therefore, the development of active photocatalytic materials has relied on both photocatalysts and cocatalysts. This review article describes the historical development of water-splitting photocatalysts.

Photocatalytic water splitting using semiconductor particles: History and recent developments

Cracking failure study of ITER-reference tungsten grade under single pulse thermal shock loads at elevated temperatures

Effects of ELMs on ITER divertor armour materials

Experimental study of PFCs erosion under ITER-like transient loads at plasma gun facility QSPA

The current ITER design employs beryllium, carbon fiber reinforced composite and tungsten as plasma facing materials. Since these materials are exposed to high heat fluxes during the operation, it is essential to perform high heat flux tests for R&D of ITER components. Static heat loads corresponding to cycling loads during normal operation, are estimated to be up to 20 MW/m 2 in the divertor targets and around 0.5 MW/m 2 at the first wall in ITER. For the static high heat flux testing, tests in electron beam facilities, particle beam facilities, IR heater and in-pile tests have been performed. Another type, more critical heat loads, which have high power densities and short durations, corresponding to transient events, i.e. plasma disruption, vertical displacement events (VDEs) and edge localized modes (ELMs) deliver considerable heat flux onto the plasma facing materials. For this purpose, tests in electron beam (short pulses), plasma gun and high power laser facilities have been carried out. The present work summarizes the features of these facilities and recent experimental results as well as the current selection of ITER plasma facing components.

Takeshi Hirai

Papers

Cracking failure study of ITER-reference tungsten grade under single pulse thermal shock loads at elevated temperatures

Effects of ELMs on ITER divertor armour materials

Experimental study of PFCs erosion under ITER-like transient loads at plasma gun facility QSPA

ITER Relevant High Heat Flux Testing on Plasma Facing Surfaces

Potentiostatic electrodeposition of cuprous oxide thin films for photovoltaic applications