T
Tania De Simone
Researcher at Monash University, Clayton campus
Publications - 4
Citations - 64
Tania De Simone is an academic researcher from Monash University, Clayton campus. The author has contributed to research in topics: Alkyne & Hydroformylation. The author has an hindex of 4, co-authored 4 publications receiving 64 citations.
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Hydroformylation of alkenes and alkynes using a heterobinuclear RhW catalyst
TL;DR: The results of these reactions have been compared with corresponding reactions using [Rh(OAc)2]2 as catalyst as mentioned in this paper, with the alkryne reaction being significantly slower.
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Isolation and characterization of hydroformylation 'intermediates' from stoichiometric reactions between phosphinoalkenes and some heterobinuclear complexes
Kevin J. Coutinho,Ronald Stanley Dickson,Gary D. Fallon,W. Roy Jackson,Tania De Simone,Brian W. Skelton,Allan H. White +6 more
TL;DR: Some heterobimetallic acyl and µ-acyl-rhodium complexes have been isolated from reactions of the phosphido-bridged complexes and their potential role as intermediates in the catalytic hydroformylation of the parent phosphines investigated and discussed in this paper.
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Phosphinoalkyne Additions to (η5-C5H5)2Rh2(μ-CO)(μ-η2:η2-CF3C2CF3): Facile Conversion of Coordinated Phosphinoalkynes to Phosphino−Enone Ligands on a Rh−Rh Bond
TL;DR: The phosphinoalkynes Ph2PC⋮CR (R = H, Me, CF3, But, Ph, and PPh2) behave as tertiary phosphines in their reactions with the dirhodium complex.
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Hetero-polynuclear complexes containing bridging diphenylphosphino-alkenes and -alkynes. The crystal structure of an Rh2{μ−ν1:ν2−P(Ph2) (CH2)3C≡CR}Co2 complex
TL;DR: In this article, a triclinic space group P 1 (Ci1, No. 2) was determined for the dirhodium-phosphinoalkene complex, where the carbonyl and phosphine ligands are predominantly trans on the RhRh bond and a small amount of the cis-isomer is formed also.