Thomas Kulp

TL;DR: In this article, the authors compared the experimentally observed relative energy content of the IR active modes with that calculated from a statistical model, and concluded that complete randomization of the energy initially deposited in the zeroth order optically excited state occurs.

TL;DR: In this article, the authors investigated the IR laser induced fluorescence from C-H stretch fundamentals, combination bands, and overtones in the region from 2800 to 3050 cm−1.

TL;DR: In this paper, the authors present a rotationally resolved infrared laser induced fluorescence spectra for dimethyl ether and methyl formate, with linewidths < 0.31 cm−1.

TL;DR: In this paper, the authors compared the experimentally observed relative energy content of the IR active modes with that calculated from a statistical model, and concluded that substantial randomization of the energy initially deposited in the zeroth order optically excited state occurs.

TL;DR: In this article, the authors studied rovibrational state mixing in acetaldehyde using infrared laser induced fluorescence and found evidence of several strong Fermi resonances between the aldehyde C-H stretch and a few overtones and combinations of lower frequency modes.