T
Tiziana Benincori
Researcher at University of Milan
Publications - 97
Citations - 1723
Tiziana Benincori is an academic researcher from University of Milan. The author has contributed to research in topics: Enantioselective synthesis & Catalysis. The author has an hindex of 23, co-authored 86 publications receiving 1594 citations. Previous affiliations of Tiziana Benincori include University of Insubria.
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Journal ArticleDOI
New Class of Chiral Diphosphine Ligands for Highly Efficient Transition Metal-Catalyzed Stereoselective Reactions: The Bis(diphenylphosphino) Five-membered Biheteroaryls.
Tiziana Benincori,Elisabetta Brenna,Franco Sannicolò,Licia Trimarco,Patrizia Antognazza,Edoardo Cesarotti,Francesco Demartin,Tullio Pilati +7 more
TL;DR: The synthesis and application of three examples of a new class of chiral (C(2)) atropisomeric diphosphines characterized by two interconnected five-membered heteroaromatic rings, with hindered rotation around the interanular bond, are described.
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2,2',5,5'-tetramethyl-4,4'-bis(diphenylphoshino)-3,3'-bithiophene: a new, very efficient, easily accessible, chiral biheteroaromatic ligand for homogeneous stereoselective catalysis
TL;DR: The four-step straightforward synthesis of enantiopure (+)- and (-)-2,2',5,5'-tetramethyl-4,4'-bis-(diphenylphoshino)-3,3'-bithiophene (tetraMe-BITIOP), a new C2-symmetry chelating ligand for transition metals, is described, starting from 2,5-dimethylthiophene.
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The First “Charm Bracelet” Conjugated Polymer: An Electroconducting Polythiophene with Covalently Bound Fullerene Moieties
Tiziana Benincori,Elisabetta Brenna,Franco Sannicolò,Licia Trimarco,Piero Sozzani,Gianni Zotti +5 more
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Chiral atropisomeric five-membered biheteroaromatic diphosphines: new ligands of the bibenzimidazole and biindole series
Tiziana Benincori,Elisabetta Brenna,Franco Sannicolò,Licia Trimarco,Patrizia Antognazza,Edoardo Cesarotti,Francesco Demartin,Tullio Pilati,Gianni Zotti +8 more
TL;DR: In this article, two chiral atropisomeric biheteroaromatic diphosphines are described: 2,2′-bis(diphenylphosphino)-1,1′-bibenzimidazole (3a) and 3,3′-dimethyl-1, 1.1.
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3,3‘-Bis(diphenylphosphino)-1,1‘-disubstituted-2,2‘-biindoles: Easily Accessible, Electron-Rich, Chiral Diphosphine Ligands for Homogeneous Enantioselective Hydrogenation of Oxoesters
TL;DR: Comparative kinetic experiments on the hydrogenation reaction of methyl acetoacetate carried out with 1a, 1c, BINAP, and other biheteroaromatic diphosphines as ligands of Ru(II) demonstrated that all the reactions follow a first-order kinetic.