In recent years, gas sensors have been increasingly used in industrial production and daily life. Metal oxide semiconductor gas sensing materials are favoured for their outstanding physical and chemical properties, low cost and simple preparation methods. However, the gas sensing mechanisms of metal oxide semiconductors have not been considered by researchers, resulting in omissions and errors in the interpretation of gas sensing mechanisms in many articles. This review organizes and introduces several common gas sensing mechanisms of metal oxide semiconductors in detail and classifies them into two categories. The scope and relationship of these mechanisms are clarified. In addition, this review selects four strategies for enhancing the gas sensing properties of metal oxide semiconductors and analyses the gas sensing mechanisms to highlight the importance of the gas sensing mechanism. Finally, some perspectives for future investigations on the gas sensing mechanisms of metal oxide semiconductors are discussed as well.

Gas sensing mechanisms of metal oxide semiconductors: a focus review

High-precision gas sensors operated at room temperature are attractive for various real-time gas monitoring applications, with advantages including low energy consumption, cost effectiveness and device miniaturization/flexibility. Studies on sensing materials, which play a key role in good gas sensing performance, are currently focused extensively on semiconducting metal oxide nanostructures (SMONs) used in the conventional resistance type gas sensors. This topical review highlights the designs and mechanisms of different SMONs with various patterns (e.g. nanoparticles, nanowires, nanosheets, nanorods, nanotubes, nanofilms, etc.) for gas sensors to detect various hazardous gases at room temperature. The key topics include (1) single phase SMONs including both n-type and p-type ones; (2) noble metal nanoparticle and metal ion modified SMONs; (3) composite oxides of SMONs; (4) composites of SMONs with carbon nanomaterials. Enhancement of the sensing performance of SMONs at room temperature can also be realized using a photo-activation effect such as ultraviolet light. SMON based mechanically flexible and wearable room temperature gas sensors are also discussed. Various mechanisms have been discussed for the enhanced sensing performance, which include redox reactions, heterojunction generation, formation of metal sulfides and the spillover effect. Finally, major challenges and prospects for the SMON based room temperature gas sensors are highlighted.

/pdf/advances-in-designs-and-mechanisms-of-semiconducting-metal-4ilnslg421.pdf

Advances in designs and mechanisms of semiconducting metal oxide nanostructures for high-precision gas sensors operated at room temperature

https://www.econstor.eu/bitstream/10419/244006/1/1693663112.pdf

Enhanced sensing performance of ZnO nanostructures-based gas sensors: A review

Zinc oxide (ZnO) is a multifunctional material due to its exceptional physicochemical properties and broad usefulness. The special properties resulting from the reduction of the material size from the macro scale to the nano scale has made the application of ZnO nanomaterials (ZnO NMs) more popular in numerous consumer products. In recent years, particular attention has been drawn to the development of various methods of ZnO NMs synthesis, which above all meet the requirements of the green chemistry approach. The application of the microwave heating technology when obtaining ZnO NMs enables the development of new methods of syntheses, which are characterised by, among others, the possibility to control the properties, repeatability, reproducibility, short synthesis duration, low price, purity, and fulfilment of the eco-friendly approach criterion. The dynamic development of materials engineering is the reason why it is necessary to obtain ZnO NMs with strictly defined properties. The present review aims to discuss the state of the art regarding the microwave synthesis of undoped and doped ZnO NMs. The first part of the review presents the properties of ZnO and new applications of ZnO NMs. Subsequently, the properties of microwave heating are discussed and compared with conventional heating and areas of application are presented. The final part of the paper presents reactants, parameters of processes, and the morphology of products, with a division of the microwave synthesis of ZnO NMs into three primary groups, namely hydrothermal, solvothermal, and hybrid methods.

A Review of Microwave Synthesis of Zinc Oxide Nanomaterials: Reactants, Process Parameters and Morphologies

/pdf/metal-oxide-nanostructures-for-sensor-applications-3fe10u79mn.pdf

Metal oxide nanostructures for sensor applications

Novel gas sensors with high sensing properties, simultaneously operating at room temperature are considerably more attractive owing to their low power consumption, high security and long-term stability. Till date, zinc oxide (ZnO) as semiconducting metal oxide is considered as the promising resistive-type gas sensing material, but elevated operating temperature becomes the bottleneck of its extensive applications in the field of real-time gas monitoring, especially in flammable and explosive gas atmosphere. In this respect, worldwide efforts have been devoted to reducing the operating temperature by means of multiple methods In this communication, room-temperature gas sensing properties of ZnO based gas sensors are comprehensively reviewed. Much more attention is particularly paid to the effective strategies that create room-temperature gas sensing of ZnO based gas sensors, mainly including surface modification, additive doping and light activation. Finally, some perspectives for future investigation on room-temperature gas-sensing materials are discussed as well.

Wen Zeng

Papers

Room-temperature gas sensing of ZnO-based gas sensor: A review