Recent advances in metal-organic framework membranes for water treatment: A review.

Abstract Biochar shows significant potential to serve as a globally applicable material to remediate water and soil owing to the extensive availability of feedstocks and conducive physio-chemical surface characteristics. This review aims to highlight biochar production technologies, characteristics of biochar, and the latest advancements in immobilizing and eliminating heavy metal ions and organic pollutants in soil and water. Pyrolysis temperature, heat transfer rate, residence time, and type of feedstock are critical influential parameters. Biochar’s efficacy in managing contaminants relies on the pore size distribution, surface groups, and ion-exchange capacity. The molecular composition and physical architecture of biochar may be crucial when practically applied to water and soil. In general, biochar produced at relatively high pyrolysis temperatures can effectively manage organic pollutants via increasing surface area, hydrophobicity and microporosity. Biochar generated at lower temperatures is deemed to be more suitable for removing polar organic and inorganic pollutants through oxygen-containing functional groups, precipitation and electrostatic attraction. This review also presents the existing obstacles and future research direction related to biochar-based materials in immobilizing organic contaminants and heavy metal ions in effluents and soil. Graphical Abstract 

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Biochar for the removal of contaminants from soil and water: a review

Abstract With social progress and industrial development, heavy metal pollution in water and soils environment is becoming more serious. Although biochar is a low-cost and environmentally friendly adsorbent for heavy metal ions, its adsorption and immobilization efficiency still need to be improved. As an upgraded version of biochar, modified biochar has attracted extensive attention in the scientific community. This review summarized the recent research progress on the treatment methods on heavy metal pollutants in water and soils using biochar. The features and advantages of biochar modification techniques such as physical modification, chemical modification, biological modification and other categories of biochar were discussed. The mechanism of removing heavy metals from soil and water by modified biochar was summarized. It was found that biochar had better performance after modification, which provided higher surface areas and more functional groups, and had enough binding sites to combine heavy metal ions. Biochar is a very promising candidate for removing heavy metals in environment. Furthermore, some high valent metal ions could be reduced to low valent metals, such as Cr(VI) reduction to Cr(III), and form precipitates on biochar by in-situ sorption-reduction-precipitation strategy. However, it is still the direction of efforts to develop high-efficiency modified biochar with low-cost, high sorption capacity, high photocatalytic performance, environmentally friendly and no secondary pollution in future. 

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Modified biochar: synthesis and mechanism for removal of environmental heavy metals

Recent advances in applications of low-cost adsorbents for the removal of heavy metals from water: A critical review

Abstract The fast increase of population results in the quick development of industry and agriculture. Large amounts of contaminants such as metal ions and organic contaminants are released into the natural environment, posing a risk to human health and causing environment ecosystem problems. The efficient elimination of contaminants from aqueous solutions, photocatalytic degradation of organic pollutants or the in-situ solidification/immobilization of heavy metal ions in solid phases are the most suitable strategies to decontaminate the pollution. Biochar and biochar-based composites have attracted multidisciplinary interests especially in environmental pollution management because of their porous structures, large amounts of functional groups, high adsorption capacities and photocatalysis performance. In this review, the application of biochar and biochar-based composites as adsorbents and/or catalysts for the adsorption of different contaminants, adsorption-photodegradation of organic pollutants, and adsorption-(photo)reduction of metal ions are summarized, and the mechanism was discussed from advanced spectroscopy analysis and DFT calculation in detail. The doping of metal or metal oxides is the main strategy to narrow the band gap, to increase the generation and separation of photogenerated e − -h + pairs, to produce more superoxide radicals (·O 2 − ) and hydroxyl radicals (·OH), to enhance the visible light absorption and to increase photocatalysis performance, which dominate the photocatalytic degradation of organic pollutants and (photo)reduction of high valent metals to low valent metals. The biochar-based composites are environmentally friendly materials, which are promising candidates in environmental pollution cleanup. The challenge and perspective for biochar-based catalysts are provided in the end. Graphical Abstract 

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Application of biochar-based photocatalysts for adsorption-(photo)degradation/reduction of environmental contaminants: mechanism, challenges and perspective

Biochar (BC) has exhibited a great potential to remove water contaminants due to its wide availability of raw materials, high surface area, developed pore structure, and low cost. However, the application of BC for water remediation has many limitations. Driven by the intense desire of overcoming unfavorable factors, a growing number of researchers have carried out to produce BC-based composite materials, which not only improved the physicochemical properties of BC, but also obtained a new composite material which combined the advantages of BC and other materials. This article reviewed previous researches on BC and BC-based composite materials, and discussed in terms of the preparation methods, the physicochemical properties, the performance of contaminant removal, and underlying adsorption mechanisms. Then the recent research progress in the removal of inorganic and organic contaminants by BC and BC-based materials was also systematically reviewed. Although BC-based composite materials have shown high performance in inorganic or organic pollutants removal, the potential risks (such as stability and biological toxicity) still need to be noticed and further study. At the end of this review, future prospects for the synthesis and application of BC and BC-based materials were proposed. This review will help the new researchers systematically understand the research progress of BC and BC-based composite materials in environmental remediation.

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Xiangke Wang

Papers

Review of organic and inorganic pollutants removal by biochar and biochar-based composites